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Cited by 163

The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.

Significant Enhancement of Hydrogen Evolution Reaction Activity by Negatively Charged Pt through Light Doping of W

Kobayashi, Daiya, Kobayashi, Hirokazu, Wu, Dongshuang, Okazoe, Shinya, Kusada, Kohei, Yamamoto, Tomokazu, Toriyama, Takaaki, Matsumura, Syo, Kawaguchi, Shogo, Kubota, Yoshiki, Aspera, Susan Meñez, Nakanishi, Hiroshi, Arai, Shigebumi, Kitagawa, Hiroshi·2020·Journal of the American Chemical Society

Abstract

We report novel PtW solid-solution nanoparticles (NPs) produced through electrochemical cleaning of core/shell PtW@WO 3 NPs. The resulting PtW NPs achieved a record hydrogen evolution reaction (HER) performance as a class of Pt-based solid-solution alloys. A current density of 10 mA cm –2 was reached with an overpotential of 19.4 mV, which is significantly lower than that of a commercial Pt catalyst (26.3 mV). The PtW NPs also exhibited long-term stability. Theoretical calculations revealed that negatively charged Pt atoms adjacent to a W atom provide favorable hydrogen adsorption energies for the HER, realizing significantly enhanced HER activity.

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Metadata

Authors
Kobayashi, D., Kobayashi, H., Wu, D., Okazoe, S., Kusada, K., Yamamoto, T., Toriyama, T., Matsumura, S., Kawaguchi, S., Kubota, Y., Aspera, S. M., Nakanishi, H., Arai, S., & Kitagawa, H.
Venue
Journal of the American Chemical Society
Published
2020-09-30
Volume
142
Issue
41
Pages
17250-17254
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W3090420807
Cited by
163
References
6
FWCI
4.72
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Significant Enhancement of Hydrogen Evolution Reaction Activity by Negatively Charged Pt through Light Doping of W. https://app.cochat.ai/papers/10.1021/jacs.0c07143
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Kobayashi, D., Kobayashi, H., Wu, D., Okazoe, S., Kusada, K., Yamamoto, T., Toriyama, T., Matsumura, S., Kawaguchi, S., Kubota, Y., Aspera, S. M., Nakanishi, H., Arai, S., & Kitagawa, H. (2020). Significant Enhancement of Hydrogen Evolution Reaction Activity by Negatively Charged Pt through Light Doping of W. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.0c07143

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.