The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Solvation Structure Design for Aqueous Zn Metal Batteries
Open accessAbstract
Aqueous Zn batteries are promising energy storage devices for large-scale energy-storage due to low cost and high energy density. However, their lifespan is limited by the water decomposition and Zn dendrite growth. Here, we suppress water reduction and Zn dendrite growth in dilute aqueous electrolyte by adding dimethyl sulfoxide (DMSO) into ZnCl 2 –H 2 O, in which DMSO replaces the H 2 O in Zn 2+ solvation sheath due to a higher Gutmann donor number (29.8) of DMSO than that (18) of H 2 O. The preferential solvation of DMSO with Zn 2+ and strong H 2 O–DMSO interaction inhibit the decomposition of solvated H 2 O. In addition, the decomposition of solvated DMSO forms Zn 12 (SO 4 ) 3 Cl 3 (OH) 15 ·5H 2 O, ZnSO 3, and ZnS enriched-solid electrolyte interphase (SEI) preventing Zn dendrite and further suppressing water decomposition. The ZnCl 2 –H 2 O–DMSO electrolyte enables Zn anodes in Zn||Ti half-cell to achieve a high average Coulombic efficiency of 99.5% for 400 cycles (400 h), and the Zn||MnO 2 full cell with a low capacity ratio of Zn:MnO 2 at 2:1 to deliver a high energy density of 212 Wh/kg (based on both cathode and anode) and maitain 95.3% of the capacity over 500 cycles at 8 C.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Aqueous Batteries Operated at −50 °C
Nian, Q., Wang, J., Liu, S., Sun, T., Zheng, S., Zhang, Y., Tao, Z., & Chen, J. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201908913 · Cited by 426
Cited by
Zeng, X., Xie, K., Liu, S., Zhang, S., Hao, J., Liu, J., Pang, W. K., Liu, J., Rao, P., Wang, Q., et al. (2021) · Energy & Environmental Science · doi:10.1039/d1ee01851e · Cited by 528
Designing Electrolyte Structure to Suppress Hydrogen Evolution Reaction in Aqueous Batteries
Nian, Q., Zhang, X., Feng, Y., Liu, S., Sun, T., Zheng, S., Ren, X., Tao, Z., Zhang, D., & Chen, J. (2021) · ACS Energy Letters · doi:10.1021/acsenergylett.1c00833 · Cited by 303
Qin, M., Liu, M., Zeng, Z., Wu, Q., Wu, Y., Zhang, H., Lei, S., Cheng, S., & Xie, J. (2022) · Advanced Energy Materials · doi:10.1002/aenm.202201801 · Cited by 138
Liu, J., Yang, C., Chi, X., Wen, B., Wang, W., & Liu, Y. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202106811 · Cited by 89
Metadata
- Authors
- Cao, L., Li, D., Hu, E., Xu, J., Deng, T., Ma, L., Wang, Y., Yang, X.-Q., & Wang, C.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2020-12-08
- Volume
- 142
- Issue
- 51
- Pages
- 21404-21409
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W3111560045
- Cited by
- 1,392
- References
- 1
- FWCI
- 52.49
- Type
- journal article
- Language
- en
- Open access
- green
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Solvation Structure Design for Aqueous Zn Metal Batteries. https://app.cochat.ai/papers/10.1021/jacs.0c09794
- The paper
- Cao, L., Li, D., Hu, E., Xu, J., Deng, T., Ma, L., Wang, Y., Yang, X.-Q., & Wang, C. (2020). Solvation Structure Design for Aqueous Zn Metal Batteries. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.0c09794
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
