The DOI matches its Crossref record; 44 of the 44 references it cites were found in a registry or an index.
Non-innocent Radical Ion Intermediates in Photoredox Catalysis: Parallel Reduction Modes Enable Coupling of Diverse Aryl Chlorides
Open accessAbstract
We describe a photocatalytic system that elicits potent photoreductant activity from conventional photocatalysts by leveraging radical anion intermediates generated in situ. The combination of isophthalonitrile and sodium formate promotes diverse aryl radical coupling reactions from abundant but difficult to reduce aryl chloride substrates. Mechanistic studies reveal two parallel pathways for substrate reduction both enabled by a key terminal reductant byproduct, carbon dioxide radical anion.
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Cites
Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
Romero, N. A., & Nicewicz, D. A. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00057 · Cited by 6,283
Visible light photoredox catalysis: applications in organic synthesis
Narayanam, J. M. R., & Stephenson, C. R. J. (2011) · Chem. Soc. Rev. · doi:10.1039/b913880n · Cited by 4,161
Bond Dissociation Energies of Organic Molecules
Blanksby, S. J., & Ellison, G. B. (2003) · ChemInform · doi:10.1002/chin.200324299 · Cited by 3,376
Photoredox Catalysis in Organic Chemistry
Shaw, M. H., Twilton, J., & MacMillan, D. W. C. (2016) · The Journal of Organic Chemistry · doi:10.1021/acs.joc.6b01449 · Cited by 3,186
Dual Catalysis Strategies in Photochemical Synthesis
Skubi, K. L., Blum, T. R., & Yoon, T. P. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00018 · Cited by 2,686
Electrocatalysis as an enabling technology for organic synthesis
Novaes, L. F. T., Liu, J., Shen, Y., Lu, L., Meinhardt, J. M., & Lin, S. (2021) · Chemical Society Reviews · doi:10.1039/d1cs00223f · Cited by 1,278
Reduction of aryl halides by consecutive visible light-induced electron transfer processes
Ghosh, I., Ghosh, T., Bardagi, J. I., & König, B. (2014) · Science · doi:10.1126/science.1258232 · Cited by 1,250
Thiyl Radicals in Organic Synthesis
Dénès, F., Pichowicz, M., Povie, G., & Renaud, P. (2014) · Chemical Reviews · doi:10.1021/cr400441m · Cited by 985
The photophysics of photoredox catalysis: a roadmap for catalyst design
Arias-Rotondo, D. M., & McCusker, J. K. (2016) · Chemical Society Reviews · doi:10.1039/c6cs00526h · Cited by 969
Cited by
Xu, J., Cao, J., Wu, X., Wang, H., Yang, X., Tang, X., Toh, R. W., Zhou, R., Yeow, E. K. L., & Wu, J. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.1c05994 · Cited by 280
Metadata
- Authors
- Chmiel, A. F., Williams, O. P., Chernowsky, C. P., Yeung, C. S., & Wickens, Z. K.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2021-07-13
- Volume
- 143
- Issue
- 29
- Pages
- 10882-10889
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W3167811481
- Cited by
- 281
- References
- 44
- FWCI
- 18.03
- Type
- journal article
- Language
- en
- Open access
- green
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- Chmiel, A. F., Williams, O. P., Chernowsky, C. P., Yeung, C. S., & Wickens, Z. K. (2021). Non-innocent Radical Ion Intermediates in Photoredox Catalysis: Parallel Reduction Modes Enable Coupling of Diverse Aryl Chlorides. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.1c05988
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
