The DOI matches its Crossref record; 37 of the 37 references it cites were found in a registry or an index.
Cooperative Rh-O5/Ni(Fe) Site for Efficient Biomass Upgrading Coupled with H2 Production
Abstract
Designing efficient and durable bifunctional catalysts for 5-hydroxymethylfurfural (HMF) oxidation reaction (HMFOR) and hydrogen evolution reaction (HER) is desirable for the co-production of biomass-upgraded chemicals and sustainable hydrogen, which is limited by the competitive adsorption of hydroxyl species (OH ads ) and HMF molecules. Here, we report a class of Rh–O 5 /Ni(Fe) atomic site on nanoporous mesh-type layered double hydroxides with atomic-scale cooperative adsorption centers for highly active and stable alkaline HMFOR and HER catalysis. A low cell voltage of 1.48 V is required to achieve 100 mA cm –2 in an integrated electrolysis system along with excellent stability (>100 h). Operando infrared and X-ray absorption spectroscopic probes unveil that HMF molecules are selectively adsorbed and activated over the single-atom Rh sites and oxidized by in situ-formed electrophilic OH ads species on neighboring Ni sites. Theoretical studies further demonstrate that the strong d–d orbital coupling interactions between atomic-level Rh and surrounding Ni atoms in the special Rh–O 5 /Ni(Fe) structure can greatly facilitate surface electronic exchange-and-transfer capabilities with the adsorbates (OH ads and HMF molecules) and intermediates for efficient HMFOR and HER. We also reveal that the Fe sites in Rh–O 5 /Ni(Fe) structure can promote the electrocatalytic stability of the catalyst. Our findings provide new insights into catalyst design for complex reactions involving competitive adsorptions of multiple intermediates.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
An Investigation of Thin-Film Ni–Fe Oxide Catalysts for the Electrochemical Evolution of Oxygen
Louie, M. W., & Bell, A. T. (2013) · Journal of the American Chemical Society · doi:10.1021/ja405351s · Cited by 2,803
Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction
Yang, H. B., Hung, S.-F., Liu, S., Yuan, K., Miao, S., Zhang, L., Huang, X., Wang, H.-Y., Cai, W., Chen, R., et al. (2018) · Nature Energy · doi:10.1038/s41560-017-0078-8 · Cited by 2,239
Considerations for the scaling-up of water splitting catalysts
Kibsgaard, J., & Chorkendorff, I. (2019) · Nature Energy · doi:10.1038/s41560-019-0407-1 · Cited by 1,329
You, B., Liu, X., Jiang, N., & Sun, Y. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b07127 · Cited by 1,001
Activity Origins and Design Principles of Nickel-Based Catalysts for Nucleophile Electrooxidation
Chen, W., Xie, C., Wang, Y., Zou, Y., Dong, C.-L., Huang, Y.-C., Xiao, Z., Wei, Z., Du, S., Chen, C., et al. (2020) · Chem · doi:10.1016/j.chempr.2020.07.022 · Cited by 814
Self-citation2D Layered Double Hydroxides for Oxygen Evolution Reaction: From Fundamental Design to Application
Lv, L., Yang, Z., Chen, K., Wang, C., & Xiong, Y. (2019) · Advanced Energy Materials · doi:10.1002/aenm.201803358 · Cited by 730
Nickel ferrocyanide as a high-performance urea oxidation electrocatalyst
Geng, S.-K., Zheng, Y., Li, S.-Q., Su, H., Zhao, X., Hu, J., Shu, H.-B., Jaroniec, M., Chen, P., Liu, Q.-H., et al. (2021) · Nature Energy · doi:10.1038/s41560-021-00899-2 · Cited by 723
Li, P., Wang, M., Duan, X., Zheng, L., Cheng, X., Zhang, Y., Kuang, Y., Li, Y., Ma, Q., Feng, Z., et al. (2019) · Nature Communications · doi:10.1038/s41467-019-09666-0 · Cited by 717
Electrocatalytic Refinery for Sustainable Production of Fuels and Chemicals
Tang, C., Zheng, Y., Jaroniec, M., & Qiao, S. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202101522 · Cited by 715
Jiang, K., Liu, B., Luo, M., Ning, S., Peng, M., Zhao, Y., Lu, Y.-R., Chan, T.-S., de Groot, F. M. F., & Tan, Y. (2019) · Nature Communications · doi:10.1038/s41467-019-09765-y · Cited by 670
Self-citation
Cited by
Bifunctional Electrocatalysts for Overall and Hybrid Water Splitting
Quan, L., Jiang, H., Mei, G., Sun, Y., & You, B. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00332 · Cited by 874
Zeng, L., Zhao, Z., Huang, Q., Zhou, C., Chen, W., Wang, K., Li, M., Lin, F., Luo, H., Gu, Y., et al. (2023) · Journal of the American Chemical Society · doi:10.1021/jacs.3c06863 · Cited by 325
Self-citationYang, Z., Wang, S., Wei, C., Chen, L., Xue, Z., & Mu, T. (2024) · Energy & Environmental Science · doi:10.1039/d3ee04543a · Cited by 169
Ren, G., Liu, B., Xu, X., Jing, P., Wu, J., & Zhang, J. (2024) · Nano Today · doi:10.1016/j.nantod.2024.102315 · Cited by 50
CuNi Aerogels with Suppressed Water Activation for Efficient Nucleophilic Methanol Electrooxidation
Fang, Q., Ye, S., Zheng, L., Wang, H., Hu, L., Gu, W., Wang, L., Shi, L., & Zhu, C. (2024) · ACS Catalysis · doi:10.1021/acscatal.4c01596 · Cited by 48
Metadata
- Authors
- Zeng, L., Chen, Y., Sun, M., Huang, Q., Sun, K., Ma, J., Li, J., Tan, H., Li, M., Pan, Y., Liu, Y., Luo, M., Huang, B., & Guo, S.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2023-05-30
- Volume
- 145
- Issue
- 32
- Pages
- 17577-17587
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W4378781696
- Cited by
- 265
- References
- 37
- FWCI
- 12.40
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Cooperative Rh-O5/Ni(Fe) Site for Efficient Biomass Upgrading Coupled with H2 Production. https://app.cochat.ai/papers/10.1021/jacs.3c02570
- The paper
- Zeng, L., Chen, Y., Sun, M., Huang, Q., Sun, K., Ma, J., Li, J., Tan, H., Li, M., Pan, Y., Liu, Y., Luo, M., Huang, B., & Guo, S. (2023). Cooperative Rh-O5/Ni(Fe) Site for Efficient Biomass Upgrading Coupled with H2 Production. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.3c02570
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
