The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Decarboxylative Fluorination of Aliphatic Carboxylic Acids via Photoredox Catalysis
Open accessAbstract
The direct conversion of aliphatic carboxylic acids to the corresponding alkyl fluorides has been achieved via visible light-promoted photoredox catalysis. This operationally simple, redox-neutral fluorination method is amenable to a wide variety of carboxylic acids. Photon-induced oxidation of carboxylates leads to the formation of carboxyl radicals, which upon rapid CO2-extrusion and F(•) transfer from a fluorinating reagent yield the desired fluoroalkanes with high efficiency. Experimental evidence indicates that an oxidative quenching pathway is operable in this broadly applicable fluorination protocol.
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Cites
Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
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Metadata
- Authors
- Ventre, S., Petronijevic, F. R., & MacMillan, D. W. C.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-04-27
- Volume
- 137
- Issue
- 17
- Pages
- 5654-5657
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2315095124
- Cited by
- 390
- References
- 1
- FWCI
- 23.97
- Type
- journal article
- Language
- en
- Open access
- green
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- Ventre, S., Petronijevic, F. R., & MacMillan, D. W. C. (2015). Decarboxylative Fluorination of Aliphatic Carboxylic Acids via Photoredox Catalysis. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.5b02244
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
