The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Metal–Organic Framework Nodes as Nearly Ideal Supports for Molecular Catalysts: NU-1000- and UiO-66-Supported Iridium Complexes
Abstract
Metal-organic frameworks with Zr6 nodes, UiO-66 and NU-1000, were investigated as supports for Ir(CO)2 and Ir(C2H4)2 complexes. A single bonding site for the iridium is identified on the nodes of NU-1000, whereas two sites are identified on UiO-66, although at low iridium loadings only one site is occupied. Density functional theory calculations provide structural results that are in good agreement with infrared and X-ray absorption fine-structure spectra. The reactivity of node-supported Ir(CO)2 with C2H4 and the catalytic activity and selectivity of the species initially present as Ir(C2H4)2 for ethylene hydrogenation and dimerization were investigated both experimentally and computationally and shown to be strongly influenced by the node.
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Cites
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
Self-citationHorike, S., Shimomura, S., & Kitagawa, S. (2009) · Nature Chemistry · doi:10.1038/nchem.444 · Cited by 2,486
Alecu, I. M., Zheng, J., Zhao, Y., & Truhlar, D. G. (2010) · Journal of Chemical Theory and Computation · doi:10.1021/ct100326h · Cited by 1,667
Cited by
Electrochemical Hydrogen Storage Materials: State-of-the-Art and Future Perspectives
Xu, X., Dong, Y., Hu, Q., Si, N., & Zhang, C. (2024) · Energy & Fuels · doi:10.1021/acs.energyfuels.3c05138 · Cited by 555
Engineering UiO‐66 Metal Organic Framework for Heterogeneous Catalysis
Dhakshinamoorthy, A., Santiago‐Portillo, A., Asiri, A. M., & Garcia, H. (2019) · ChemCatChem · doi:10.1002/cctc.201801452 · Cited by 298
Metadata
- Authors
- Yang, D., Odoh, S. O., Wang, T. C., Farha, O. K., Hupp, J. T., Cramer, C. J., Gagliardi, L., & Gates, B. C.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-06-02
- Volume
- 137
- Issue
- 23
- Pages
- 7391-7396
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2418077897
- Cited by
- 255
- References
- 3
- FWCI
- 13.90
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yang, D., Odoh, S. O., Wang, T. C., Farha, O. K., Hupp, J. T., Cramer, C. J., Gagliardi, L., & Gates, B. C. (2015). Metal–Organic Framework Nodes as Nearly Ideal Supports for Molecular Catalysts: NU-1000- and UiO-66-Supported Iridium Complexes. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.5b02956
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