The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Stable Cobalt Nanoparticles and Their Monolayer Array as an Efficient Electrocatalyst for Oxygen Evolution Reaction
Abstract
Monodisperse cobalt (Co) nanoparticles (NPs) were synthesized and stabilized against oxidation via reductive annealing at 600 °C. The stable Co NPs are active for catalyzing the oxygen evolution reaction (OER) in 0.1 M KOH, producing a current density of 10 mA/cm(2) at an overpotential of 0.39 V (1.62 V vs RHE, no iR-correction). Their catalysis is superior to the commercial Ir catalyst in both activity and stability. These Co NPs are also assembled into a monolayer array on the working electrode, allowing the detailed study of their intrinsic OER activity. The Co NPs in the monolayer array show 15 times higher turnover frequency (2.13 s(-1)) and mass activity (1949 A/g) than the NPs deposited on conventional carbon black (0.14 s(-1) and 126 A/g, respectively) at an overpotential of 0.4 V. These stable Co NPs are a promising new class of noble-metal-free catalyst for water splitting.
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Cites
Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction
McCrory, C. C. L., Jung, S., Peters, J. C., & Jaramillo, T. F. (2013) · Journal of the American Chemical Society · doi:10.1021/ja407115p · Cited by 7,026
Enhancing Hydrogen Evolution Activity in Water Splitting by Tailoring Li + -Ni(OH) 2 -Pt Interfaces
Subbaraman, R., Tripkovic, D., Strmcnik, D., Chang, K.-C., Uchimura, M., Paulikas, A. P., Stamenkovic, V., & Markovic, N. M. (2011) · Science · doi:10.1126/science.1211934 · Cited by 3,135
Kim, D., Resasco, J., Yu, Y., Asiri, A. M., & Yang, P. (2014) · Nature Communications · doi:10.1038/ncomms5948 · Cited by 1,374
Cited by
Transition‐Metal (Co, Ni, and Fe)‐Based Electrocatalysts for the Water Oxidation Reaction
Han, L., Dong, S., & Wang, E. (2016) · Advanced Materials · doi:10.1002/adma.201602270 · Cited by 1,769
Etched and doped Co9S8/graphene hybrid for oxygen electrocatalysis
Dou, S., Tao, L., Huo, J., Wang, S., & Dai, L. (2016) · Energy & Environmental Science · doi:10.1039/c6ee00054a · Cited by 836
Jiao, L., Zhou, Y.-X., & Jiang, H.-L. (2016) · Chemical Science · doi:10.1039/c5sc04425a · Cited by 798
Organic Phase Syntheses of Magnetic Nanoparticles and Their Applications
Wu, L., Mendoza-Garcia, A., Li, Q., & Sun, S. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00687 · Cited by 601
Self-citationCopper Cobalt Sulfide Nanosheets Realizing a Promising Electrocatalytic Oxygen Evolution Reaction
Chauhan, M., Reddy, K. P., Gopinath, C. S., & Deka, S. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b01831 · Cited by 533
Metadata
- Authors
- Wu, L., Li, Q., Wu, C. H., Zhu, H., Mendoza-Garcia, A., Shen, B., Guo, J., & Sun, S.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-06-01
- Volume
- 137
- Issue
- 22
- Pages
- 7071-7074
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W754403829
- Cited by
- 336
- References
- 3
- FWCI
- 16.32
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wu, L., Li, Q., Wu, C. H., Zhu, H., Mendoza-Garcia, A., Shen, B., Guo, J., & Sun, S. (2015). Stable Cobalt Nanoparticles and Their Monolayer Array as an Efficient Electrocatalyst for Oxygen Evolution Reaction. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.5b04142
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