The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
A Cu25 Nanocluster with Partial Cu(0) Character
Abstract
Atomically precise copper nanoclusters (NCs) are of immense interest for a variety of applications, but have remained elusive. Herein, we report the isolation of a copper NC, [Cu25H22(PPh3)12]Cl (1), from the reaction of Cu(OAc) and CuCl with Ph2SiH2, in the presence of PPh3. Complex 1 has been fully characterized, including analysis by X-ray crystallography, XANES, and XPS. In the solid state, complex 1 is constructed around a Cu13 centered-icosahedron and formally features partial Cu(0) character. XANES of 1 reveals a Cu K-edge at 8979.6 eV, intermediate between the edge energies of Cu(0) and Cu(I), confirming our oxidation state assignment. This assignment is further corroborated by determination of the Auger parameter for 1, which also falls between those recorded for Cu(0) and Cu(I).
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Cites
Li, C. W., & Kanan, M. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja3010978 · Cited by 2,000
Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper
Li, C. W., Ciston, J., & Kanan, M. W. (2014) · Nature · doi:10.1038/nature13249 · Cited by 1,728
Theoretical Considerations on the Electroreduction of CO to C 2 Species on Cu(100) Electrodes
Calle‐Vallejo, F., & Koper, M. T. M. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201301470 · Cited by 941
Cited by
Liu, Y., Li, Q., Si, R., Li, G., Li, W., Liu, D., Wang, D., Sun, L., Zhang, Y., & Zou, X. (2017) · Advanced Materials · doi:10.1002/adma.201606200 · Cited by 448
Tang, Q., Lee, Y., Li, D.-Y., Choi, W., Liu, C. W., Lee, D., & Jiang, D.-E. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b05591 · Cited by 382
Atomically precise copper nanoclusters and their applications
Liu, X., & Astruc, D. (2018) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2018.01.001 · Cited by 322
Chemical Flexibility of Atomically Precise Metal Clusters
Li, S., Li, N.-N., Dong, X.-Y., Zang, S.-Q., & Mak, T. C. W. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00896 · Cited by 280
Metadata
- Authors
- Nguyen, T.-A. D., Jones, Z. R., Goldsmith, B. R., Buratto, W. R., Wu, G., Scott, S. L., & Hayton, T. W.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-10-13
- Volume
- 137
- Issue
- 41
- Pages
- 13319-13324
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2336168480
- Cited by
- 322
- References
- 3
- FWCI
- 8.66
- Type
- journal article
- Language
- en
- Open access
- closed
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Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
