Cited by 941CO2 Reduction Techniques and CatalystsCatalysts for Methane ReformingElectrocatalysts for Energy Conversion

Theoretical Considerations on the Electroreduction of CO to C 2 Species on Cu(100) Electrodes

Calle‐Vallejo, Federico, Koper, Marc T. M.·2013·Angewandte Chemie International Edition

Abstract

CO-products: DFT calculations are used to construct a mechanism for the electrochemical reduction of CO on Cu(100) that agrees with the experimental observations (see picture) of pH independence in the formation of C2 species. The rate-determining step is an electron-transfer-mediated CO dimerization. Ethylene, acetaldehyde, and ethanol are formed through a common pathway, and adsorbed ethylene oxide is one of the reaction intermediates.

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Crossref · 10.1002/anie.201301470

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Authors
Calle‐Vallejo, F., & Koper, M. T. M.
Affiliations
Leiden University (NL)
Corresponding author
Koper, Marc T. M.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2013-06-03
Volume
52
Issue
28
Pages
7282-7285
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2158532118
Cited by
941
References
31
Citations by year
2026: 59 · 2025: 106 · 2024: 106 · 2023: 102 · 2022: 104 · 2021: 95 · 2020: 92 · 2019: 80 · 2018: 60 · 2017: 49 · 2016: 43 · 2015: 30 · 2014: 12 · 2013: 3
FWCI
10.65
Type
journal article
Language
en
Open access
closed
Locations
  • Angewandte Chemie International Edition (publishedVersion)
  • PubMed (publishedVersion)
Topics
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
  • Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
Keywords
CO dimerization, C2+ products, reaction mechanism, rate-determining step, electron transfer, ethylene, acetaldehyde, ethanol, pH independence, adsorbed intermediates

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