The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Operando Analysis of NiFe and Fe Oxyhydroxide Electrocatalysts for Water Oxidation: Detection of Fe4+ by Mössbauer Spectroscopy
Abstract
Nickel-iron oxides/hydroxides are among the most active electrocatalysts for the oxygen evolution reaction. In an effort to gain insight into the role of Fe in these catalysts, we have performed operando Mössbauer spectroscopic studies of a 3:1 Ni:Fe layered hydroxide and a hydrous Fe oxide electrocatalyst. The catalysts were prepared by a hydrothermal precipitation method that enabled catalyst growth directly on carbon paper electrodes. Fe(4+) species were detected in the NiFe hydroxide catalyst during steady-state water oxidation, accounting for up to 21% of the total Fe. In contrast, no Fe(4+) was detected in the Fe oxide catalyst. The observed Fe(4+) species are not kinetically competent to serve as the active site in water oxidation; however, their presence has important implications for the role of Fe in NiFe oxide electrocatalysts.
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Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction
McCrory, C. C. L., Jung, S., Peters, J. C., & Jaramillo, T. F. (2013) · Journal of the American Chemical Society · doi:10.1021/ja407115p · Cited by 7,026
The Mechanism of Water Oxidation: From Electrolysis via Homogeneous to Biological Catalysis
Dau, H., Limberg, C., Reier, T., Risch, M., Roggan, S., & Strasser, P. (2010) · ChemCatChem · doi:10.1002/cctc.201000126 · Cited by 1,783
Wang, H., Lee, H.-W., Deng, Y., Lu, Z., Hsu, P.-C., Liu, Y., Lin, D., & Cui, Y. (2015) · Nature Communications · doi:10.1038/ncomms8261 · Cited by 1,257
Doyle, R. L., & Lyons, M. E. G. (2013) · Journal of The Electrochemical Society · doi:10.1149/2.015303jes · Cited by 238
Cited by
Electrocatalysis for the oxygen evolution reaction: recent development and future perspectives
Suen, N.-T., Hung, S.-F., Quan, Q., Zhang, N., Xu, Y.-J., & Chen, H. M. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00328a · Cited by 6,307
Chatenet, M., Pollet, B. G., Dekel, D. R., Dionigi, F., Deseure, J., Millet, P., Braatz, R. D., Bazant, M. Z., Eikerling, M., Staffell, I., et al. (2022) · Chemical Society Reviews · doi:10.1039/d0cs01079k · Cited by 2,025
Direct Electrolytic Splitting of Seawater: Opportunities and Challenges
Dresp, S., Dionigi, F., Klingenhof, M., & Strasser, P. (2019) · ACS Energy Letters · doi:10.1021/acsenergylett.9b00220 · Cited by 1,272
Metallic nanostructures with low dimensionality for electrochemical water splitting
Li, L., Wang, P., Shao, Q., & Huang, X. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00013b · Cited by 1,049
Jiang, J., Sun, F., Zhou, S., Hu, W., Zhang, H., Dong, J., Jiang, Z., Zhao, J., Li, J., Yan, W., et al. (2018) · Nature Communications · doi:10.1038/s41467-018-05341-y · Cited by 1,020
Metadata
- Authors
- Chen, J. Y. C., Dang, L., Liang, H., Bi, W., Gerken, J. B., Jin, S., Alp, E. E., & Stahl, S. S.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-11-25
- Volume
- 137
- Issue
- 48
- Pages
- 15090-15093
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2268456782
- Cited by
- 872
- References
- 4
- FWCI
- 16.32
- Type
- journal article
- Language
- en
- Open access
- closed
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- Chen, J. Y. C., Dang, L., Liang, H., Bi, W., Gerken, J. B., Jin, S., Alp, E. E., & Stahl, S. S. (2015). Operando Analysis of NiFe and Fe Oxyhydroxide Electrocatalysts for Water Oxidation: Detection of Fe4+ by Mössbauer Spectroscopy. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.5b10699
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