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Transition-Metal-Free CO-Releasing BODIPY Derivatives Activatable by Visible to NIR Light as Promising Bioactive Molecules
Abstract
Carbon monoxide-releasing molecules (CORMs) are chemical agents used to administer CO as an endogenous, biologically active molecule. A precise spatial and temporal control over the CO release is the major requirement for their applications. Here, we report the synthesis and properties of a new generation of transition-metal-free carbon monoxide-releasing molecules based on BODIPY chromophores (COR-BDPs) activatable by visible-to-NIR (up to 730 nm) light. We demonstrate their performance for both in vitro and in vivo experimental settings, and we propose the mechanism of the CO release based on steady-state and transient spectroscopy experiments and quantum chemical calculations.
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Cited by
Family of BODIPY Photocages Cleaved by Single Photons of Visible/Near-Infrared Light
Peterson, J. A., Wijesooriya, C., Gehrmann, E. J., Mahoney, K. M., Goswami, P. P., Albright, T. R., Syed, A., Dutton, A. S., Smith, E. A., & Winter, A. H. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b04040 · Cited by 299
BODIPY Derivatives for Photodynamic Therapy: Influence of Configuration versus Heavy Atom Effect
Zou, J., Yin, Z., Ding, K., Tang, Q., Li, J., Si, W., Shao, J., Zhang, Q., Huang, W., & Dong, X. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b07569 · Cited by 267
Taking phototherapeutics from concept to clinical launch
Vickerman, B. M., Zywot, E. M., Tarrant, T. K., & Lawrence, D. S. (2021) · Nature Reviews Chemistry · doi:10.1038/s41570-021-00326-w · Cited by 201
Near‐IR Photochemistry for Biology: Exploiting the Optical Window of Tissue
Alabugin, A. (2019) · Photochemistry and Photobiology · doi:10.1111/php.13068 · Cited by 70
Metadata
- Authors
- Palao, E., Slanina, T., Muchová, L., Šolomek, T., Vítek, L., & Klán, P.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-12-23
- Volume
- 138
- Issue
- 1
- Pages
- 126-133
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2238911903
- Cited by
- 291
- References
- 0
- FWCI
- 9.65
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Transition-Metal-Free CO-Releasing BODIPY Derivatives Activatable by Visible to NIR Light as Promising Bioactive Molecules. https://app.cochat.ai/papers/10.1021/jacs.5b10800
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- Palao, E., Slanina, T., Muchová, L., Šolomek, T., Vítek, L., & Klán, P. (2016). Transition-Metal-Free CO-Releasing BODIPY Derivatives Activatable by Visible to NIR Light as Promising Bioactive Molecules. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.5b10800
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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