The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Synthesis of a Chiral Crystal Form of MOF-5, CMOF-5, by Chiral Induction
Abstract
Chiral variants of the prototypal metal-organic framework MOF-5, Λ-CMOF-5 and Δ-CMOF-5, have been synthesized by preparing MOF-5 in the presence of L-proline or D-proline, respectively. CMOF-5 crystallizes in chiral space group P213 instead of Fm3̅m as exhibited by MOF-5. The phase purity of CMOF-5 was validated by single-crystal and powder X-ray diffraction, infrared spectroscopy, thermogravimetric analysis, N2 adsorption, microanalysis, and solid-state vibrational circular dichroism. CMOF-5 undergoes a reversible single crystal-to-single crystal phase change to MOF-5 when immersed in a variety of organic solvents, although N-methyl-2-pyrrolidone (NMP) does not induce loss of chirality. Indeed, MOF-5 undergoes chiral induction when immersed in NMP, affording racemic CMOF-5.
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Cites
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
Cited by
Metal–Organic Frameworks for Separation
Zhao, X., Wang, Y., Li, D., Bu, X., & Feng, P. (2018) · Advanced Materials · doi:10.1002/adma.201705189 · Cited by 1,305
Self-citationChiral Metal–Organic Frameworks
Gong, W., Chen, Z., Dong, J., Liu, Y., & Cui, Y. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00740 · Cited by 579
Chiral covalent organic frameworks: design, synthesis and property
Han, X., Yuan, C., Hou, B., Liu, L., Li, H., Liu, Y., & Cui, Y. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00009d · Cited by 478
Peluso, P., & Chankvetadze, B. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00846 · Cited by 371
Xia, Q., Li, Z., Tan, C., Liu, Y., Gong, W., & Cui, Y. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b03113 · Cited by 265
Metadata
- Authors
- Zhang, S.-Y., Li, D., Guo, D., Zhang, H., Shi, W., Cheng, P., Wojtas, L., & Zaworotko, M. J.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-12-04
- Volume
- 137
- Issue
- 49
- Pages
- 15406-15409
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2239455673
- Cited by
- 176
- References
- 1
- FWCI
- 7.36
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhang, S.-Y., Li, D., Guo, D., Zhang, H., Shi, W., Cheng, P., Wojtas, L., & Zaworotko, M. J. (2015). Synthesis of a Chiral Crystal Form of MOF-5, CMOF-5, by Chiral Induction. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.5b11150
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