The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Conversion of CO2 from Air into Methanol Using a Polyamine and a Homogeneous Ruthenium Catalyst
Abstract
A highly efficient homogeneous catalyst system for the production of CH3OH from CO2 using pentaethylenehexamine and Ru-Macho-BH (1) at 125-165 °C in an ethereal solvent has been developed (initial turnover frequency = 70 h(-1) at 145 °C). Ease of separation of CH3OH is demonstrated by simple distillation from the reaction mixture. The robustness of the catalytic system was shown by recycling the catalyst over five runs without significant loss of activity (turnover number > 2000). Various sources of CO2 can be used for this reaction including air, despite its low CO2 concentration (400 ppm). For the first time, we have demonstrated that CO2 captured from air can be directly converted to CH3OH in 79% yield using a homogeneous catalytic system.
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Cites
Noble metal-free hydrogen evolution catalysts for water splitting
Zou, X., & Zhang, Y. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00448e · Cited by 5,955
Post-Combustion CO 2 Capture Using Solid Sorbents: A Review
Samanta, A., Zhao, A., Shimizu, G. K. H., Sarkar, P., & Gupta, R. (2012) · Industrial & Engineering Chemistry Research · doi:10.1021/ie200686q · Cited by 1,889
Air as the renewable carbon source of the future: an overview of CO2 capture from the atmosphere
Goeppert, A., Czaun, M., Surya Prakash, G. K., & Olah, G. A. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21586a · Cited by 724
Self-citationNegative emissions physically needed to keep global warming below 2 °C
Gasser, T., Guivarch, C., Tachiiri, K., Jones, C. D., & Ciais, P. (2015) · Nature Communications · doi:10.1038/ncomms8958 · Cited by 374
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Direct air capture: process technology, techno-economic and socio-political challenges
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Long, R., Li, Y., Liu, Y., Chen, S., Zheng, X., Gao, C., He, C., Chen, N., Qi, Z., Song, L., et al. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b00452 · Cited by 571
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Metadata
- Authors
- Kothandaraman, J., Goeppert, A., Czaun, M., Olah, G. A., & Prakash, G. K. S.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-01-13
- Volume
- 138
- Issue
- 3
- Pages
- 778-781
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2199304650
- Cited by
- 584
- References
- 4
- FWCI
- 20.07
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kothandaraman, J., Goeppert, A., Czaun, M., Olah, G. A., & Prakash, G. K. S. (2016). Conversion of CO2 from Air into Methanol Using a Polyamine and a Homogeneous Ruthenium Catalyst. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.5b12354
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