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Cited by 375

The DOI matches its Crossref record; 44 of the 44 references it cites were found in a registry or an index.

Graphdiyne: A Metal-Free Material as Hole Transfer Layer To Fabricate Quantum Dot-Sensitized Photocathodes for Hydrogen Production

Li, Jian, Gao, Xin, Liu, Bin, Feng, Qingliang, Li, Xu-Bing, Huang, Mao-Yong, Liu, Zhongfan, Zhang, Jin, Tung, Chen-Ho, Wu, Li-Zhu·2016·Journal of the American Chemical Society

Abstract

Graphdiyne (GDY), a novel large π-conjugated carbon material, for the first time, is introduced as the hole transfer layer into a photoelectrochemical water splitting cell (PEC). Raman and ultraviolet photoelectron spectroscopic studies indicate the existence of relatively strong π-π interactions between GDY and 4-mercaptopyridine surface-functionalized CdSe quantum dots, beneficial to the hole transportation and enhancement of the photocurrent performance. Upon exposure to a Xe lamp, the integrated photocathode produces a current density of nearly -70 μA cm(-2) at a potential of 0 V vs NHE in neutral aqueous solution. Simultaneously, the photocathode evolves H2 with 90 ± 5% faradic efficiency over three times and exhibits good stability within 12 h. All of the results indicate that GDY is a promising hole transfer material to fabricate a PEC device for water splitting by solar energy.

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Metadata

Authors
Li, J., Gao, X., Liu, B., Feng, Q., Li, X.-B., Huang, M.-Y., Liu, Z., Zhang, J., Tung, C.-H., & Wu, L.-Z.
Venue
Journal of the American Chemical Society
Published
2016-03-18
Volume
138
Issue
12
Pages
3954-3957
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2295326161
Cited by
375
References
44
FWCI
13.05
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Graphdiyne: A Metal-Free Material as Hole Transfer Layer To Fabricate Quantum Dot-Sensitized Photocathodes for Hydrogen Production. https://app.cochat.ai/papers/10.1021/jacs.5b12758
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Li, J., Gao, X., Liu, B., Feng, Q., Li, X.-B., Huang, M.-Y., Liu, Z., Zhang, J., Tung, C.-H., & Wu, L.-Z. (2016). Graphdiyne: A Metal-Free Material as Hole Transfer Layer To Fabricate Quantum Dot-Sensitized Photocathodes for Hydrogen Production. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.5b12758

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