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A New Deep-Ultraviolet Transparent Orthophosphate LiCs2PO4 with Large Second Harmonic Generation Response
Abstract
LiCs2PO4, a new deep-ultraviolet (UV) transparent material, was synthesized by the flux method. The material contains unusual edge-sharing LiO4-PO4 tetrahedra. It exhibits a very short absorption edge of λ = 174 nm and generates the largest powder second harmonic generation (SHG) response for deep-UV phosphates that do not contain additional anionic groups, i.e., 2.6 times that of KH2PO4 (KDP). First-principles electronic structure analyses confirm the experimental results and suggest that the strong SHG response may originate from the aligned nonbonding O-2p orbitals. The discovery and characterization of LiCs2PO4 provide a new insight into the structure-property relationships of phosphate-based nonlinear optical materials with large SHG responses and short absorption edges.
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THE PRINCIPLES DETERMINING THE STRUCTURE OF COMPLEX IONIC CRYSTALS
Pauling, L. (1929) · Journal of the American Chemical Society · doi:10.1021/ja01379a006 · Cited by 2,025
Cited by
Two Non-π-Conjugated Deep-UV Nonlinear Optical Sulfates
Li, Y., Liang, F., Zhao, S., Li, L., Wu, Z., Ding, Q., Liu, S., Lin, Z., Hong, M., & Luo, J. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b00138 · Cited by 268
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Metadata
- Authors
- Li, L., Wang, Y., Lei, B.-H., Han, S., Yang, Z., Poeppelmeier, K. R., & Pan, S.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-07-18
- Volume
- 138
- Issue
- 29
- Pages
- 9101-9104
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2474076123
- Cited by
- 384
- References
- 1
- FWCI
- 13.00
- Type
- journal article
- Language
- en
- Open access
- closed
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- Li, L., Wang, Y., Lei, B.-H., Han, S., Yang, Z., Poeppelmeier, K. R., & Pan, S. (2016). A New Deep-Ultraviolet Transparent Orthophosphate LiCs2PO4 with Large Second Harmonic Generation Response. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.6b06053
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