The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Constructing Crystalline Covalent Organic Frameworks from Chiral Building Blocks
Abstract
Covalent organic frameworks (COFs) represent a new type of crystalline porous materials that are covalently assembled from organic building blocks. Construction of functional COFs is, however, a difficult task because it has to meet simultaneously the requirements for crystallinity and functionality. We report herein a facile strategy for the direct construction of chiral-functionalized COFs from chiral building blocks. The key design is to use the rigid scaffold 4,4'-(1H-benzo[d]imidazole-4,7-diyl)dianiline (2) for attaching a variety of chiral moieties. As a first example, the chiral pyrrolidine-embedded building block (S)-4,4'-(2-(pyrrolidin-2-yl)-1H-benzo[d]imidazole-4,7-diyl)dianiline (3) was accordingly synthesized and applied for the successful construction of two chiral COFs, LZU-72 and LZU-76. Our experimental results further showed that these chiral COFs are structurally robust and highly active as heterogeneous organocatalysts.
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Citations
Cites
Supramolecular Chirality in Self-Assembled Systems
Liu, M., Zhang, L., & Wang, T. (2015) · Chemical Reviews · doi:10.1021/cr500671p · Cited by 2,250
Cited by
Liu, R., Tan, K. T., Gong, Y., Chen, Y., Li, Z., Xie, S., He, T., Lu, Z., Yang, H., & Jiang, D. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00620c · Cited by 1,083
Porous Polymers as Multifunctional Material Platforms toward Task‐Specific Applications
Wu, J., Xu, F., Li, S., Ma, P., Zhang, X., Liu, Q., Fu, R., & Wu, D. (2019) · Advanced Materials · doi:10.1002/adma.201802922 · Cited by 555
Beuerle, F., & Gole, B. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201710190 · Cited by 528
EL-Mahdy, A. F. M., Kuo, C.-H., Alshehri, A., Young, C., Yamauchi, Y., Kim, J., & Kuo, S.-W. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta04781b · Cited by 253
Metadata
- Authors
- Xu, H.-S., Ding, S.-Y., An, W.-K., Wu, H., & Wang, W.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-09-06
- Volume
- 138
- Issue
- 36
- Pages
- 11489-11492
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2513069131
- Cited by
- 350
- References
- 1
- FWCI
- 18.48
- Type
- journal article
- Language
- en
- Open access
- closed
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- Xu, H.-S., Ding, S.-Y., An, W.-K., Wu, H., & Wang, W. (2016). Constructing Crystalline Covalent Organic Frameworks from Chiral Building Blocks. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.6b07516
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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