The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Constructing Crystalline Covalent Organic Frameworks from Chiral Building Blocks
Abstract
Covalent organic frameworks (COFs) represent a new type of crystalline porous materials that are covalently assembled from organic building blocks. Construction of functional COFs is, however, a difficult task because it has to meet simultaneously the requirements for crystallinity and functionality. We report herein a facile strategy for the direct construction of chiral-functionalized COFs from chiral building blocks. The key design is to use the rigid scaffold 4,4'-(1H-benzo[d]imidazole-4,7-diyl)dianiline (2) for attaching a variety of chiral moieties. As a first example, the chiral pyrrolidine-embedded building block (S)-4,4'-(2-(pyrrolidin-2-yl)-1H-benzo[d]imidazole-4,7-diyl)dianiline (3) was accordingly synthesized and applied for the successful construction of two chiral COFs, LZU-72 and LZU-76. Our experimental results further showed that these chiral COFs are structurally robust and highly active as heterogeneous organocatalysts.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Supramolecular Chirality in Self-Assembled Systems
Liu, M., Zhang, L., & Wang, T. (2015) · Chemical Reviews · doi:10.1021/cr500671p · Cited by 2,250
Cited by
Covalent Organic Frameworks: Structures, Synthesis, and Applications
Lohse, M. S., & Bein, T. (2018) · Advanced Functional Materials · doi:10.1002/adfm.201705553 · Cited by 1,527
Liu, R., Tan, K. T., Gong, Y., Chen, Y., Li, Z., Xie, S., He, T., Lu, Z., Yang, H., & Jiang, D. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00620c · Cited by 1,083
Post-synthetic modification of covalent organic frameworks
Segura, J. L., Royuela, S., & Mar Ramos, M. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00978c · Cited by 832
Chen, R., Shi, J., Ma, Y., Lin, G., Lang, X., & Wang, C. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201902543 · Cited by 697
Covalent–Organic Frameworks: Advanced Organic Electrode Materials for Rechargeable Batteries
Sun, T., Xie, J., Guo, W., Li, D., & Zhang, Q. (2020) · Advanced Energy Materials · doi:10.1002/aenm.201904199 · Cited by 622
Metadata
- Authors
- Xu, H.-S., Ding, S.-Y., An, W.-K., Wu, H., & Wang, W.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-09-06
- Volume
- 138
- Issue
- 36
- Pages
- 11489-11492
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2513069131
- Cited by
- 350
- References
- 1
- FWCI
- 18.48
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
