The DOI matches its Crossref record.
Palladium-Catalyzed Regio- and Enantioselective Synthesis of Allylic Amines Featuring Tetrasubstituted Tertiary Carbons
Open accessAbstract
The first asymmetric synthesis of α,α-disubstituted allylic N-arylamines based on a palladium-catalyzed allylic amination has been developed. The protocol uses highly modular vinyl cyclic carbonates and unactivated aromatic amine nucleophiles as substrates. The catalytic process features minimal waste production, ample scope in reaction partners, high asymmetric induction up to 97% ee, and operational simplicity.
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Citations
Cited by
Alves, M., Grignard, B., Mereau, R., Jerome, C., Tassaing, T., & Detrembleur, C. (2017) · Catalysis Science & Technology · doi:10.1039/c7cy00438a · Cited by 531
Catalytic Transformations of Functionalized Cyclic Organic Carbonates
Guo, W., Gómez, J. E., Cristòfol, À., Xie, J., & Kleij, A. W. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201805009 · Cited by 371
Self-citationMetal-catalyzed regiodivergent organic reactions
Nájera, C., Beletskaya, I. P., & Yus, M. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00872h · Cited by 304
Metadata
- Authors
- Cai, A., Guo, W., Martínez-Rodríguez, L., & Kleij, A. W.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-10-21
- Volume
- 138
- Issue
- 43
- Pages
- 14194-14197
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2533049456
- Cited by
- 207
- References
- 0
- FWCI
- 11.29
- Type
- journal article
- Language
- en
- Open access
- green
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- CoChat. (2026). Citation check: Palladium-Catalyzed Regio- and Enantioselective Synthesis of Allylic Amines Featuring Tetrasubstituted Tertiary Carbons. https://app.cochat.ai/papers/10.1021/jacs.6b08841
- The paper
- Cai, A., Guo, W., Martínez-Rodríguez, L., & Kleij, A. W. (2016). Palladium-Catalyzed Regio- and Enantioselective Synthesis of Allylic Amines Featuring Tetrasubstituted Tertiary Carbons. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.6b08841
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
