The DOI matches its Crossref record; 37 of the 37 references it cites were found in a registry or an index.
Plasmon-Enhanced Photocatalytic CO2 Conversion within Metal–Organic Frameworks under Visible Light
Open accessAbstract
Materials development for artificial photosynthesis, in particular, CO 2 reduction, has been under extensive efforts, ranging from inorganic semiconductors to molecular complexes. In this report, we demonstrate a metal–organic framework (MOF)-coated nanoparticle photocatalyst with enhanced CO 2 reduction activity and stability, which stems from having two different functional units for activity enhancement and catalytic stability combined together as a single construct. Covalently attaching a CO 2 -to-CO conversion photocatalyst Re I (CO) 3 (BPYDC)Cl, BPYDC = 2,2′-bipyridine-5,5′-dicarboxylate, to a zirconium MOF, UiO-67 (Re n -MOF), prevents dimerization leading to deactivation. By systematically controlling its density in the framework ( n = 0, 1, 2, 3, 5, 11, 16, and 24 complexes per unit cell), the highest photocatalytic activity was found for Re 3 -MOF. Structural analysis of Re n -MOFs suggests that a fine balance of proximity between photoactive centers is needed for cooperatively enhanced photocatalytic activity, where an optimum number of Re complexes per unit cell should reach the highest activity. Based on the structure–activity correlation of Re n -MOFs, Re 3 -MOF was coated onto Ag nanocubes (Ag⊂Re 3 -MOF), which spatially confined photoactive Re centers to the intensified near-surface electric fields at the surface of Ag nanocubes, resulting in a 7-fold enhancement of CO 2 -to-CO conversion under visible light with long-term stability maintained up to 48 h.
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Cites
The Chemistry and Applications of Metal-Organic Frameworks
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Self-citationA New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
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Plasmonic-metal nanostructures for efficient conversion of solar to chemical energy
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Titanium Dioxide-Based Nanomaterials for Photocatalytic Fuel Generations
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Metal–organic frameworks for artificial photosynthesis and photocatalysis
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Light-Driven Heterogeneous Reduction of Carbon Dioxide: Photocatalysts and Photoelectrodes
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Cited by
What Should We Make with CO2 and How Can We Make It?
Bushuyev, O. S., De Luna, P., Dinh, C. T., Tao, L., Saur, G., van de Lagemaat, J., Kelley, S. O., & Sargent, E. H. (2018) · Joule · doi:10.1016/j.joule.2017.09.003 · Cited by 1,593
Single Pt Atoms Confined into a Metal–Organic Framework for Efficient Photocatalysis
Fang, X., Shang, Q., Wang, Y., Jiao, L., Yao, T., Li, Y., Zhang, Q., Luo, Y., & Jiang, H. (2018) · Advanced Materials · doi:10.1002/adma.201705112 · Cited by 837
Pristine Metal–Organic Frameworks and their Composites for Energy Storage and Conversion
Liang, Z., Qu, C., Guo, W., Zou, R., & Xu, Q. (2018) · Advanced Materials · doi:10.1002/adma.201702891 · Cited by 787
The role of reticular chemistry in the design of CO2 reduction catalysts
Diercks, C. S., Liu, Y., Cordova, K. E., & Yaghi, O. M. (2018) · Nature Materials · doi:10.1038/s41563-018-0033-5 · Cited by 721
Self-citationMetal–organic frameworks as a platform for clean energy applications
Li, X., Yang, X., Xue, H., Pang, H., & Xu, Q. (2020) · EnergyChem · doi:10.1016/j.enchem.2020.100027 · Cited by 706
Metadata
- Authors
- Choi, K. M., Kim, D., Rungtaweevoranit, B., Trickett, C. A., Barmanbek, J. T. D., Alshammari, A. S., Yang, P., & Yaghi, O. M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-12-22
- Volume
- 139
- Issue
- 1
- Pages
- 356-362
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2551981773
- Cited by
- 632
- References
- 37
- FWCI
- 18.41
- Type
- journal article
- Language
- en
- Open access
- green
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- Choi, K. M., Kim, D., Rungtaweevoranit, B., Trickett, C. A., Barmanbek, J. T. D., Alshammari, A. S., Yang, P., & Yaghi, O. M. (2017). Plasmon-Enhanced Photocatalytic CO2 Conversion within Metal–Organic Frameworks under Visible Light. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.6b11027
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