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In Situ Probes of Capture and Decomposition of Chemical Warfare Agent Simulants by Zr-Based Metal Organic Frameworks
Open accessAbstract
Zr-based metal organic frameworks (MOFs) have been recently shown to be among the fastest catalysts of nerve-agent hydrolysis in solution. We report a detailed study of the adsorption and decomposition of a nerve-agent simulant, dimethyl methylphosphonate (DMMP), on UiO-66, UiO-67, MOF-808, and NU-1000 using synchrotron-based X-ray powder diffraction, X-ray absorption, and infrared spectroscopy, which reveals key aspects of the reaction mechanism. The diffraction measurements indicate that all four MOFs adsorb DMMP (introduced at atmospheric pressures through a flow of helium or air) within the pore space. In addition, the combination of X-ray absorption and infrared spectra suggests direct coordination of DMMP to the Zr 6 cores of all MOFs, which ultimately leads to decomposition to phosphonate products. These experimental probes into the mechanism of adsorption and decomposition of chemical warfare agent simulants on Zr-based MOFs open new opportunities in rational design of new and superior decontamination materials.
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Citations
Cites
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
Cited by
Hadjiivanov, K. I., Panayotov, D. A., Mihaylov, M. Y., Ivanova, E. Z., Chakarova, K. K., Andonova, S. M., & Drenchev, N. L. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00487 · Cited by 1,278
Defective Metal‐Organic Frameworks
Dissegna, S., Epp, K., Heinz, W. R., Kieslich, G., & Fischer, R. A. (2018) · Advanced Materials · doi:10.1002/adma.201704501 · Cited by 728
Sensing and capture of toxic and hazardous gases and vapors by metal–organic frameworks
Wang, H., Lustig, W. P., & Li, J. (2018) · Chemical Society Reviews · doi:10.1039/c7cs00885f · Cited by 695
Bioinspired Framework Catalysts: From Enzyme Immobilization to Biomimetic Catalysis
Wang, K.-Y., Zhang, J., Hsu, Y.-C., Lin, H., Han, Z., Pang, J., Yang, Z., Liang, R.-R., Shi, W., & Zhou, H.-C. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00879 · Cited by 490
Kirlikovali, K. O., Chen, Z., Islamoglu, T., Hupp, J. T., & Farha, O. K. (2020) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.9b20154 · Cited by 286
Metadata
- Authors
- Plonka, A. M., Wang, Q., Gordon, W. O., Balboa, A., Troya, D., Guo, W., Sharp, C. H., Senanayake, S. D., Morris, J. R., Hill, C. L., & Frenkel, A. I.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-01-05
- Volume
- 139
- Issue
- 2
- Pages
- 599-602
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2562136744
- Cited by
- 208
- References
- 1
- FWCI
- 10.31
- Type
- journal article
- Language
- en
- Open access
- green
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- Plonka, A. M., Wang, Q., Gordon, W. O., Balboa, A., Troya, D., Guo, W., Sharp, C. H., Senanayake, S. D., Morris, J. R., Hill, C. L., & Frenkel, A. I. (2017). In Situ Probes of Capture and Decomposition of Chemical Warfare Agent Simulants by Zr-Based Metal Organic Frameworks. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.6b11373
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