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Cited by 877

The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.

Highly Oriented Low-Dimensional Tin Halide Perovskites with Enhanced Stability and Photovoltaic Performance

Open access
Liao, Yuqin, Liu, Hefei, Zhou, Wenjia, Yang, Dongwen, Shang, Yuequn, Shi, Zhifang, Li, Binghan, Jiang, Xianyuan, Zhang, Lijun, Quan, Li Na, Quintero-Bermudez, Rafael, Sutherland, Brandon R., Mi, Qixi, Sargent, Edward H., Ning, Zhijun·2017·Journal of the American Chemical Society

Abstract

The low toxicity and a near-ideal choice of bandgap make tin perovskite an attractive alternative to lead perovskite in low cost solar cells. However, the development of Sn perovskite solar cells has been impeded by their extremely poor stability when exposed to oxygen. We report low-dimensional Sn perovskites that exhibit markedly enhanced air stability in comparison with their 3D counterparts. The reduced degradation under air exposure is attributed to the improved thermodynamic stability after dimensional reduction, the encapsulating organic ligands, and the compact perovskite film preventing oxygen ingress. We then explore these highly oriented low-dimensional Sn perovskite films in solar cells. The perpendicular growth of the perovskite domains between electrodes allows efficient charge carrier transport, leading to power conversion efficiencies of 5.94% without the requirement of further device structure engineering. We tracked the performance of unencapsulated devices over 100 h and found no appreciable decay in efficiency. These findings raise the prospects of pure Sn perovskites for solar cells application.

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Metadata

Authors
Liao, Y., Liu, H., Zhou, W., Yang, D., Shang, Y., Shi, Z., Li, B., Jiang, X., Zhang, L., Quan, L. N., Quintero-Bermudez, R., Sutherland, B. R., Mi, Q., Sargent, E. H., & Ning, Z.
Venue
Journal of the American Chemical Society
Published
2017-05-02
Volume
139
Issue
19
Pages
6693-6699
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2609670982
Cited by
877
References
3
FWCI
41.95
Type
journal article
Language
en
Open access
green

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The paper
Liao, Y., Liu, H., Zhou, W., Yang, D., Shang, Y., Shi, Z., Li, B., Jiang, X., Zhang, L., Quan, L. N., Quintero-Bermudez, R., Sutherland, B. R., Mi, Q., Sargent, E. H., & Ning, Z. (2017). Highly Oriented Low-Dimensional Tin Halide Perovskites with Enhanced Stability and Photovoltaic Performance. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.7b01815

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.