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Visible-Light-Driven Carboxylation of Aryl Halides by the Combined Use of Palladium and Photoredox Catalysts
Abstract
A highly useful, visible-light-driven carboxylation of aryl bromides and chlorides with CO 2 was realized using a combination of Pd(OAc) 2 as a carboxylation catalyst and Ir(ppy) 2 (dtbpy)(PF 6 ) as a photoredox catalyst. This carboxylation reaction proceeded in high yields under 1 atm of CO 2 with a variety of functionalized aryl bromides and chlorides without the necessity of using stoichiometric metallic reductants.
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Cited by
Metallaphotoredox: The Merger of Photoredox and Transition Metal Catalysis
Chan, A. Y., Perry, I. B., Bissonnette, N. B., Buksh, B. F., Edwards, G. A., Frye, L. I., Garry, O. L., Lavagnino, M. N., Li, B. X., Liang, Y., et al. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00383 · Cited by 1,754
Visible-Light-Driven Reductive Carboarylation of Styrenes with CO 2 and Aryl Halides
Wang, H., Gao, Y., Zhou, C., & Li, G. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c03144 · Cited by 303
Direct electrochemical defluorinative carboxylation of α-CF 3 alkenes with carbon dioxide
Gao, X.-T., Zhang, Z., Wang, X., Tian, J.-S., Xie, S.-L., Zhou, F., & Zhou, J. (2020) · Chemical Science · doi:10.1039/d0sc04091f · Cited by 142
Metadata
- Authors
- Shimomaki, K., Murata, K., Martin, R., & Iwasawa, N.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-07-05
- Volume
- 139
- Issue
- 28
- Pages
- 9467-9470
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2725381093
- Cited by
- 274
- References
- 0
- FWCI
- 13.05
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Visible-Light-Driven Carboxylation of Aryl Halides by the Combined Use of Palladium and Photoredox Catalysts. https://app.cochat.ai/papers/10.1021/jacs.7b04838
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- Shimomaki, K., Murata, K., Martin, R., & Iwasawa, N. (2017). Visible-Light-Driven Carboxylation of Aryl Halides by the Combined Use of Palladium and Photoredox Catalysts. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.7b04838
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