Student or educator? Sign up with your school email and get 6 months of Pro free.
Cited by 142

The DOI matches its Crossref record; 103 of the 103 references it cites were found in a registry or an index.

Direct electrochemical defluorinative carboxylation of α-CF 3 alkenes with carbon dioxide

Gao, Xiao-Tong, Zhang, Zheng, Wang, Xin, Tian, Jun-Song, Xie, Shi-Liang, Zhou, Feng, Zhou, Jian·2020·Chemical Science

Abstract

A γ-carboxylation of α-CF 3 alkenes with CO 2 using platinum plate as both working cathode and nonsacrificial anode has been developed.

Overview

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Integrity signals

Registry

Crossref · 10.1039/d0sc04091f

Cites

103 of 103 references verified0 citation errors · 0 not checkable

Statistics

Figures

Scheme 1 C–F bond carboxylation with CO2.
Scheme 1 C–F bond carboxylation with CO2.CC BY · PubMed Central
Scheme 2 Synthetic elaboration of 2a.
Scheme 2 Synthetic elaboration of 2a.CC BY · PubMed Central
Fig. 1 CV analysis of 1a. nBu4NClO4 (0.07 M) in DMF as electrolyte and a 100 mV s−1 scan rate using a Pt disk WE and Pt pillar CE along with Ag/AgNO3 as RE.
Fig. 1 CV analysis of 1a. nBu4NClO4 (0.07 M) in DMF as electrolyte and a 100 mV s−1 scan rate using a Pt disk WE and Pt pillar CE along with Ag/AgNO3 as RE.CC BY · PubMed Central
Scheme 3 Control experiments. Standard conditions: constant current electrolysis under 8 mA using Pt-plate as cathode and anode with nBu4NClO4 (0.07 M) in DMF, 7 hours.
Scheme 3 Control experiments. Standard conditions: constant current electrolysis under 8 mA using Pt-plate as cathode and anode with nBu4NClO4 (0.07 M) in DMF, 7 hours.CC BY · PubMed Central
Fig. 2 DFT calculations. Gibbs free-energy profile for possible reaction channels at the IEFPCM-M06-2X/6-311++G(d,p) level in solvent DMF.
Fig. 2 DFT calculations. Gibbs free-energy profile for possible reaction channels at the IEFPCM-M06-2X/6-311++G(d,p) level in solvent DMF.CC BY · PubMed Central
Fig. 3 Proposed reaction mechanism.
Fig. 3 Proposed reaction mechanism.CC BY · PubMed Central

Verification

Claims the paper makes

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Claims other papers make about this one

Each is checked against this paper’s own text: does it say what the citing paper says it does?

Self-check

Percentages, sums and reported differences re-computed from the paper’s own numbers.

The self-check needs the paper’s full text.

Citations

Cites

Show all 103 references

Metadata

Authors
Gao, X.-T., Zhang, Z., Wang, X., Tian, J.-S., Xie, S.-L., Zhou, F., & Zhou, J.
Affiliations
  • Shanghai Key Laboratory of Green Chemistry and Chemical Processes
  • College of Chemistry
Venue
Chemical Science
Published
2020
Volume
11
Issue
38
Pages
10414-10420
ISSN
  • 2041-6520
  • 2041-6539
Cited by
142
References
103
Language
en
Funders
  • National Natural Science Foundation of China (21871090)
  • Fundamental Research Funds for the Central Universities
  • Ministry of Education of the People's Republic of China

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

How to cite

Cite CoChat for the checks on this page, and the paper for its own findings.

This page
CoChat. (2026). Citation check: Direct electrochemical defluorinative carboxylation of α-CF 3 alkenes with carbon dioxide. https://app.cochat.ai/papers/10.1039/d0sc04091f
The paper
Gao, X.-T., Zhang, Z., Wang, X., Tian, J.-S., Xie, S.-L., Zhou, F., & Zhou, J. (2020). Direct electrochemical defluorinative carboxylation of α-CF 3 alkenes with carbon dioxide. Chemical Science. https://doi.org/10.1039/d0sc04091f

Data sources

Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.