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Pore-Engineered Metal–Organic Frameworks with Excellent Adsorption of Water and Fluorocarbon Refrigerant for Cooling Applications
Abstract
Metal-organic frameworks (MOFs) have shown promising behavior for adsorption cooling applications. Using organic ligands with 1, 2, and 3 phenylene rings, we construct moisture-stable Ni-MOF-74 members with adjustable pore apertures, which exhibit excellent sorption capabilities toward water and fluorocarbon R134a. To our knowledge, this is the first report of adsorption isotherms of fluorocarbon R134a in MOFs. The adsorption patterns for these materials differ significantly and are attributed to variances in their hydrophobic/hydrophilic pore character associated with differences in pore size.
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Cited by
Hadjiivanov, K. I., Panayotov, D. A., Mihaylov, M. Y., Ivanova, E. Z., Chakarova, K. K., Andonova, S. M., & Drenchev, N. L. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00487 · Cited by 1,278
Sensing and capture of toxic and hazardous gases and vapors by metal–organic frameworks
Wang, H., Lustig, W. P., & Li, J. (2018) · Chemical Society Reviews · doi:10.1039/c7cs00885f · Cited by 695
Nanoconfined phase change materials for thermal energy applications
Aftab, W., Huang, X., Wu, W., Liang, Z., Mahmood, A., & Zou, R. (2018) · Energy & Environmental Science · doi:10.1039/c7ee03587j · Cited by 647
Water and Metal–Organic Frameworks: From Interaction toward Utilization
Liu, X., Wang, X., & Kapteijn, F. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00746 · Cited by 614
Ligand Rigidification for Enhancing the Stability of Metal–Organic Frameworks
Lv, X.-L., Yuan, S., Xie, L.-H., Darke, H. F., Chen, Y., He, T., Dong, C., Wang, B., Zhang, Y.-Z., Li, J.-R., et al. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b02947 · Cited by 322
Metadata
- Authors
- Zheng, J., Vemuri, R. S., Estevez, L., Koech, P. K., Varga, T., Camaioni, D. M., Blake, T. A., McGrail, B. P., & Motkuri, R. K.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-07-20
- Volume
- 139
- Issue
- 31
- Pages
- 10601-10604
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2735797865
- Cited by
- 177
- References
- 0
- FWCI
- 6.90
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- Zheng, J., Vemuri, R. S., Estevez, L., Koech, P. K., Varga, T., Camaioni, D. M., Blake, T. A., McGrail, B. P., & Motkuri, R. K. (2017). Pore-Engineered Metal–Organic Frameworks with Excellent Adsorption of Water and Fluorocarbon Refrigerant for Cooling Applications. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.7b04872
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