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Dithienopicenocarbazole-Based Acceptors for Efficient Organic Solar Cells with Optoelectronic Response Over 1000 nm and an Extremely Low Energy Loss
Abstract
Two cheliform non-fullerene acceptors, DTPC-IC and DTPC-DFIC, based on a highly electron-rich core, dithienopicenocarbazole (DTPC), are synthesized, showing ultra-narrow bandgaps (as low as 1.21 eV). The two-dimensional nitrogen-containing conjugated DTPC possesses strong electron-donating capability, which induces intense intramolecular charge transfer and intermolecular π-π stacking in derived acceptors. The solar cell based on DTPC-DFIC and a spectrally complementary polymer donor, PTB7-Th, showed a high power conversion efficiency of 10.21% and an extremely low energy loss of 0.45 eV, which is the lowest among reported efficient OSCs.
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Metadata
- Authors
- Yao, Z., Liao, X., Gao, K., Lin, F., Xu, X., Shi, X., Zuo, L., Liu, F., Chen, Y., & Jen, A. K.-Y.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-02-05
- Volume
- 140
- Issue
- 6
- Pages
- 2054-2057
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2786015244
- Cited by
- 403
- References
- 37
- FWCI
- 29.35
- Type
- journal article
- Language
- en
- Open access
- closed
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