The DOI matches its Crossref record; 27 of the 27 references it cites were found in a registry or an index.
Enhanced Out-of-Plane Conductivity and Photovoltaic Performance in n = 1 Layered Perovskites through Organic Cation Design
Open accessAbstract
Layered perovskites with the formula (R–NH 3 ) 2 PbI 4 have excellent environmental stability but poor photovoltaic function due to the preferential orientation of the semiconducting layer parallel to the substrate and the typically insulating nature of the R–NH 3 + cation. Here, we report a series of these n = 1 layered perovskites with the form (aromatic- O -linker-NH 3 ) 2 PbI 4 where the aromatic moiety is naphthalene, pyrene, or perylene and the linker is ethyl, propyl, or butyl. These materials achieve enhanced conductivity perpendicular to the inorganic layers due to better energy level matching between the inorganic layers and organic galleries. The enhanced conductivity and visible absorption of these materials led to a champion power conversion efficiency of 1.38%, which is the highest value reported for any n = 1 layered perovskite, and it is an order of magnitude higher efficiency than any other n = 1 layered perovskite oriented with layers parallel to the substrate. These findings demonstrate the importance of leveraging the electronic character of the organic cation to improve optoelectronic properties and thus the photovoltaic performance of these chemically stable low n layered perovskites.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Saliba, M., Matsui, T., Seo, J.-Y., Domanski, K., Correa-Baena, J.-P., Nazeeruddin, M. K., Zakeeruddin, S. M., Tress, W., Abate, A., Hagfeldt, A., et al. (2016) · Energy & Environmental Science · doi:10.1039/c5ee03874j · Cited by 5,440
Charge Transport in Organic Semiconductors
Coropceanu, V., Cornil, J., da Silva Filho, D. A., Olivier, Y., Silbey, R., & Brédas, J.-L. (2007) · Chemical Reviews · doi:10.1021/cr050140x · Cited by 4,607
High-efficiency two-dimensional Ruddlesden–Popper perovskite solar cells
Tsai, H., Nie, W., Blancon, J.-C., Stoumpos, C. C., Asadpour, R., Harutyunyan, B., Neukirch, A. J., Verduzco, R., Crochet, J. J., Tretiak, S., et al. (2016) · Nature · doi:10.1038/nature18306 · Cited by 3,384
Organic–Inorganic Perovskites: Structural Versatility for Functional Materials Design
Saparov, B., & Mitzi, D. B. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00715 · Cited by 2,907
Li, Z., Yang, M., Park, J.-S., Wei, S.-H., Berry, J. J., & Zhu, K. (2016) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b04107 · Cited by 2,269
2D Homologous Perovskites as Light-Absorbing Materials for Solar Cell Applications
Cao, D. H., Stoumpos, C. C., Farha, O. K., Hupp, J. T., & Kanatzidis, M. G. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b03796 · Cited by 2,158
Ruddlesden–Popper Hybrid Lead Iodide Perovskite 2D Homologous Semiconductors
Stoumpos, C. C., Cao, D. H., Clark, D. J., Young, J., Rondinelli, J. M., Jang, J. I., Hupp, J. T., & Kanatzidis, M. G. (2016) · Chemistry of Materials · doi:10.1021/acs.chemmater.6b00847 · Cited by 2,130
A Layered Hybrid Perovskite Solar‐Cell Absorber with Enhanced Moisture Stability
Smith, I. C., Hoke, E. T., Solis‐Ibarra, D., McGehee, M. D., & Karunadasa, H. I. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201406466 · Cited by 2,011
Elastomeric Transistor Stamps: Reversible Probing of Charge Transport in Organic Crystals
Sundar, V. C., Zaumseil, J., Podzorov, V., Menard, E., Willett, R. L., Someya, T., Gershenson, M. E., & Rogers, J. A. (2004) · Science · doi:10.1126/science.1094196 · Cited by 1,640
Molecular Manipulation of Microstructures: Biomaterials, Ceramics, and Semiconductors
Stupp, S. I., & Braun, P. V. (1997) · Science · doi:10.1126/science.277.5330.1242 · Cited by 817
Self-citation
Cited by
Li, X., Hoffman, J. M., & Kanatzidis, M. G. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c01006 · Cited by 1,085
Gharibzadeh, S., Abdollahi Nejand, B., Jakoby, M., Abzieher, T., Hauschild, D., Moghadamzadeh, S., Schwenzer, J. A., Brenner, P., Schmager, R., Haghighirad, A. A., et al. (2019) · Advanced Energy Materials · doi:10.1002/aenm.201803699 · Cited by 435
Lyu, R., Moore, C. E., Liu, T., Yu, Y., & Wu, Y. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.1c05441 · Cited by 114
Metadata
- Authors
- Passarelli, J. V., Fairfield, D. J., Sather, N. A., Hendricks, M. P., Sai, H., Stern, C. L., & Stupp, S. I.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-06-05
- Volume
- 140
- Issue
- 23
- Pages
- 7313-7323
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2805059700
- Cited by
- 365
- References
- 27
- FWCI
- 13.27
- Type
- journal article
- Language
- en
- Open access
- green
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Enhanced Out-of-Plane Conductivity and Photovoltaic Performance in n = 1 Layered Perovskites through Organic Cation Design. https://app.cochat.ai/papers/10.1021/jacs.8b03659
- The paper
- Passarelli, J. V., Fairfield, D. J., Sather, N. A., Hendricks, M. P., Sai, H., Stern, C. L., & Stupp, S. I. (2018). Enhanced Out-of-Plane Conductivity and Photovoltaic Performance in n = 1 Layered Perovskites through Organic Cation Design. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.8b03659
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
