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Cited by 578

The DOI matches its Crossref record; 50 of the 50 references it cites were found in a registry or an index.

Colloidal Synthesis of Double Perovskite Cs2AgInCl6 and Mn-Doped Cs2AgInCl6 Nanocrystals

Open access
Locardi, Federico, Cirignano, Matilde, Baranov, Dmitry, Dang, Zhiya, Prato, Mirko, Drago, Filippo, Ferretti, Maurizio, Pinchetti, Valerio, Fanciulli, Marco, Brovelli, Sergio, De Trizio, Luca, Manna, Liberato·2018·Journal of the American Chemical Society

Abstract

Abstract We show here the first colloidal synthesis of double perovskite Cs2AgInCl6 nanocrystals (NCs) with a control over their size distribution. In our approach, metal carboxylate precursors and ligands (oleylamine and oleic acid) are dissolved in diphenyl ether and reacted at 105 °C with benzoyl chloride. The resulting Cs2AgInCl6 NCs exhibit the expected double perovskite crystal structure, are stable under air, and show a broad spectrum white photoluminescence (PL) with quantum yield of ∼1.6 ± 1%. The optical properties of these NCs were improved by synthesizing Mn-doped Cs2AgInCl6 NCs through the simple addition of Mn-acetate to the reaction mixture. The NC products were characterized by the same double perovskite crystal structure, and Mn doping levels up to 1.5%, as confirmed by elemental analyses. The effective incorporation of Mn ions inside Cs2AgInCl6 NCs was also proved by means of electron spin resonance spectroscopy. A bright orange emission characterized our Mn-doped Cs2AgInCl6 NCs with a PL quantum yield as high as ∼16 ± 4%.

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Crossref · 10.1021/jacs.8b07983

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Metadata

Authors
Locardi, F., Cirignano, M., Baranov, D., Dang, Z., Prato, M., Drago, F., Ferretti, M., Pinchetti, V., Fanciulli, M., Brovelli, S., De Trizio, L., & Manna, L.
Venue
Journal of the American Chemical Society
Published
2018-09-10
Volume
140
Issue
40
Pages
12989-12995
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2891026324
Cited by
578
References
50
FWCI
20.32
Type
journal article
Language
en
Open access
hybrid

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Locardi, F., Cirignano, M., Baranov, D., Dang, Z., Prato, M., Drago, F., Ferretti, M., Pinchetti, V., Fanciulli, M., Brovelli, S., De Trizio, L., & Manna, L. (2018). Colloidal Synthesis of Double Perovskite Cs2AgInCl6 and Mn-Doped Cs2AgInCl6 Nanocrystals. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.8b07983

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.