The DOI matches its Crossref record; 50 of the 50 references it cites were found in a registry or an index.
Colloidal Synthesis of Double Perovskite Cs2AgInCl6 and Mn-Doped Cs2AgInCl6 Nanocrystals
Open accessAbstract
Abstract We show here the first colloidal synthesis of double perovskite Cs2AgInCl6 nanocrystals (NCs) with a control over their size distribution. In our approach, metal carboxylate precursors and ligands (oleylamine and oleic acid) are dissolved in diphenyl ether and reacted at 105 °C with benzoyl chloride. The resulting Cs2AgInCl6 NCs exhibit the expected double perovskite crystal structure, are stable under air, and show a broad spectrum white photoluminescence (PL) with quantum yield of ∼1.6 ± 1%. The optical properties of these NCs were improved by synthesizing Mn-doped Cs2AgInCl6 NCs through the simple addition of Mn-acetate to the reaction mixture. The NC products were characterized by the same double perovskite crystal structure, and Mn doping levels up to 1.5%, as confirmed by elemental analyses. The effective incorporation of Mn ions inside Cs2AgInCl6 NCs was also proved by means of electron spin resonance spectroscopy. A bright orange emission characterized our Mn-doped Cs2AgInCl6 NCs with a PL quantum yield as high as ∼16 ± 4%.
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Saliba, M., Matsui, T., Seo, J.-Y., Domanski, K., Correa-Baena, J.-P., Nazeeruddin, M. K., Zakeeruddin, S. M., Tress, W., Abate, A., Hagfeldt, A., et al. (2016) · Energy & Environmental Science · doi:10.1039/c5ee03874j · Cited by 5,440
Genesis, challenges and opportunities for colloidal lead halide perovskite nanocrystals
Akkerman, Q. A., Rainò, G., Kovalenko, M. V., & Manna, L. (2018) · Nature Materials · doi:10.1038/s41563-018-0018-4 · Cited by 2,287
Self-citationSlavney, A. H., Hu, T., Lindenberg, A. M., & Karunadasa, H. I. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.5b13294 · Cited by 2,204
Optical properties of manganese-doped nanocrystals of ZnS
Bhargava, R. N., Gallagher, D., Hong, X., & Nurmikko, A. (1994) · Physical Review Letters · doi:10.1103/physrevlett.72.416 · Cited by 1,994
Cs2AgBiX6 (X = Br, Cl): New Visible Light Absorbing, Lead-Free Halide Perovskite Semiconductors
McClure, E. T., Ball, M. R., Windl, W., & Woodward, P. M. (2016) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b04231 · Cited by 1,674
Bismuth Based Hybrid Perovskites A3Bi2I9 (A: Methylammonium or Cesium) for Solar Cell Application
Park, B., Philippe, B., Zhang, X., Rensmo, H., Boschloo, G., & Johansson, E. M. J. (2015) · Advanced Materials · doi:10.1002/adma.201501978 · Cited by 1,269
Cs2InAgCl6: A New Lead-Free Halide Double Perovskite with Direct Band Gap
Volonakis, G., Haghighirad, A. A., Milot, R. L., Sio, W. H., Filip, M. R., Wenger, B., Johnston, M. B., Herz, L. M., Snaith, H. J., & Giustino, F. (2017) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b02682 · Cited by 1,176
Lead-Free Halide Double Perovskites via Heterovalent Substitution of Noble Metals
Volonakis, G., Filip, M. R., Haghighirad, A. A., Sakai, N., Wenger, B., Snaith, H. J., & Giustino, F. (2016) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b00376 · Cited by 1,146
Toward Lead-Free Perovskite Solar Cells
Giustino, F., & Snaith, H. J. (2016) · ACS Energy Letters · doi:10.1021/acsenergylett.6b00499 · Cited by 1,141
Design of Lead-Free Inorganic Halide Perovskites for Solar Cells via Cation-Transmutation
Zhao, X.-G., Yang, J.-H., Fu, Y., Yang, D., Xu, Q., Yu, L., Wei, S.-H., & Zhang, L. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b09645 · Cited by 1,003
Cited by
Rare-Earth Doping in Nanostructured Inorganic Materials
Zheng, B., Fan, J., Chen, B., Qin, X., Wang, J., Wang, F., Deng, R., & Liu, X. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00644 · Cited by 1,204
Bi3+‐Er3+ and Bi3+‐Yb3+ Codoped Cs2AgInCl6 Double Perovskite Near‐Infrared Emitters
Arfin, H., Kaur, J., Sheikh, T., Chakraborty, S., & Nag, A. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202002721 · Cited by 359
Mn2+‐Doped Metal Halide Perovskites: Structure, Photoluminescence, and Application
Su, B., Zhou, G., Huang, J., Song, E., Nag, A., & Xia, Z. (2021) · Laser & Photonics Reviews · doi:10.1002/lpor.202000334 · Cited by 319
Emissive Bi-Doped Double Perovskite Cs2Ag1–xNaxInCl6 Nanocrystals
Locardi, F., Sartori, E., Buha, J., Zito, J., Prato, M., Pinchetti, V., Zaffalon, M. L., Ferretti, M., Brovelli, S., Infante, I., et al. (2019) · ACS Energy Letters · doi:10.1021/acsenergylett.9b01274 · Cited by 268
Self-citation
Metadata
- Authors
- Locardi, F., Cirignano, M., Baranov, D., Dang, Z., Prato, M., Drago, F., Ferretti, M., Pinchetti, V., Fanciulli, M., Brovelli, S., De Trizio, L., & Manna, L.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-09-10
- Volume
- 140
- Issue
- 40
- Pages
- 12989-12995
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2891026324
- Cited by
- 578
- References
- 50
- FWCI
- 20.32
- Type
- journal article
- Language
- en
- Open access
- hybrid
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