The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Visible-Light-Driven Conversion of CO2 to CH4 with an Organic Sensitizer and an Iron Porphyrin Catalyst
Open accessAbstract
Using a phenoxazine-based organic photosensitizer and an iron porphyrin molecular catalyst, we demonstrated photochemical reduction of CO 2 to CO and CH 4 with turnover numbers (TONs) of 149 and 29, respectively, under visible-light irradiation (λ > 435 nm) with a tertiary amine as sacrificial electron donor. This work is the first example of a molecular system using an earth-abundant metal catalyst and an organic dye to effect complete 8e – /8H + reduction of CO 2 to CH 4, as opposed to typical 2e – /2H + products of CO or formic acid. The catalytic system continuously produced methane even after prolonged irradiation up to 4 days. Using CO as the feedstock, the same reactive system was able to produce CH 4 with 85% selectivity, 80 TON and a quantum yield of 0.47%. The redox properties of the organic photosensitizer and acidity of the proton source were shown to play a key role in driving the 8e – /8H + processes.
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Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO 2 Fixation
Appel, A. M., Bercaw, J. E., Bocarsly, A. B., Dobbek, H., DuBois, D. L., Dupuis, M., Ferry, J. G., Fujita, E., Hille, R., Kenis, P. J. A., et al. (2013) · Chemical Reviews · doi:10.1021/cr300463y · Cited by 2,193
Long, R., Li, Y., Liu, Y., Chen, S., Zheng, X., Gao, C., He, C., Chen, N., Qi, Z., Song, L., et al. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b00452 · Cited by 571
Cited by
Metallaphotoredox: The Merger of Photoredox and Transition Metal Catalysis
Chan, A. Y., Perry, I. B., Bissonnette, N. B., Buksh, B. F., Edwards, G. A., Frye, L. I., Garry, O. L., Lavagnino, M. N., Li, B. X., Liang, Y., et al. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00383 · Cited by 1,754
Boutin, E., Merakeb, L., Ma, B., Boudy, B., Wang, M., Bonin, J., Anxolabéhère-Mallart, E., & Robert, M. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00218f · Cited by 423
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Metadata
- Authors
- Rao, H., Lim, C.-H., Bonin, J., Miyake, G. M., & Robert, M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-12-07
- Volume
- 140
- Issue
- 51
- Pages
- 17830-17834
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2904893302
- Cited by
- 225
- References
- 3
- FWCI
- 4.41
- Type
- journal article
- Language
- en
- Open access
- green
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- Rao, H., Lim, C.-H., Bonin, J., Miyake, G. M., & Robert, M. (2018). Visible-Light-Driven Conversion of CO2 to CH4 with an Organic Sensitizer and an Iron Porphyrin Catalyst. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.8b09740
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