The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Reverse Dual-Ion Battery via a ZnCl2 Water-in-Salt Electrolyte
Open accessAbstract
Dual-ion batteries are known for anion storage in the cathode coupled to cation incorporation in the anode. We flip the sequence of the anion/cation-storage chemistries of the anode and the cathode in dual-ion batteries (DIBs) by allowing the anode to take in anions and a cation-deficient cathode to host cations, thus operating as a reverse dual-ion battery (RDIB). The anion-insertion anode is a nanocomposite having ferrocene encapsulated inside a microporous carbon, and the cathode is a Zn-insertion Prussian blue, Zn 3 [Fe(CN) 6 ] 2 . This unique battery configuration benefits from the usage of a 30 m ZnCl 2 “water-in-salt” electrolyte. This electrolyte minimizes the dissolution of ferrocene; it raises the cation-insertion potential in the cathode, and it depresses the anion-insertion potential in the anode, thus widening the full cell’s voltage by 0.35 V compared with a dilute ZnCl 2 electrolyte. RDIBs provide a configuration-based solution to exploit the practicality of cation-deficient cathode materials in aqueous electrolytes.
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Cites
“Water-in-salt” electrolyte enables high-voltage aqueous lithium-ion chemistries
Suo, L., Borodin, O., Gao, T., Olguin, M., Ho, J., Fan, X., Luo, C., Wang, C., & Xu, K. (2015) · Science · doi:10.1126/science.aab1595 · Cited by 3,821
Cited by
Li, M., Li, Z., Wang, X., Meng, J., Liu, X., Wu, B., Han, C., & Mai, L. (2021) · Energy & Environmental Science · doi:10.1039/d1ee00030f · Cited by 559
A chemically self-charging aqueous zinc-ion battery
Zhang, Y., Wan, F., Huang, S., Wang, S., Niu, Z., & Chen, J. (2020) · Nature Communications · doi:10.1038/s41467-020-16039-5 · Cited by 406
Yu, M., Chandrasekhar, N., Raghupathy, R. K. M., Ly, K. H., Zhang, H., Dmitrieva, E., Liang, C., Lu, X., Kühne, T. D., Mirhosseini, H., et al. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c07992 · Cited by 406
Hydrophobic Organic‐Electrolyte‐Protected Zinc Anodes for Aqueous Zinc Batteries
Cao, L., Li, D., Deng, T., Li, Q., & Wang, C. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202008634 · Cited by 401
Wang, C., Pei, Z., Meng, Q., Zhang, C., Sui, X., Yuan, Z., Wang, S., & Chen, Y. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202012030 · Cited by 394
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Metadata
- Authors
- Wu, X., Xu, Y., Zhang, C., Leonard, D. P., Markir, A., Lu, J., & Ji, X.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-03-28
- Volume
- 141
- Issue
- 15
- Pages
- 6338-6344
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2935349668
- Cited by
- 481
- References
- 1
- FWCI
- 23.26
- Type
- journal article
- Language
- en
- Open access
- green
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- Wu, X., Xu, Y., Zhang, C., Leonard, D. P., Markir, A., Lu, J., & Ji, X. (2019). Reverse Dual-Ion Battery via a ZnCl2 Water-in-Salt Electrolyte. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.9b00617
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