The DOI matches its Crossref record; 15 of the 15 references it cites were found in a registry or an index.
Hydrophobic Organic‐Electrolyte‐Protected Zinc Anodes for Aqueous Zinc Batteries
Abstract
Aqueous Zn batteries are promising energy‐storage devices. However, their lifespan is limited by irreversible Zn anodes owing to water decomposition and Zn dendrite growth. Here, we separate aqueous electrolyte from Zn anode by coating a thin MOF layer on anode and filling the pores of MOF with hydrophobic Zn(TFSI)2‐tris(2,2,2‐trifluoroethyl)phosphate (TFEP) organic electrolyte that is immiscible with aqueous Zn(TFSI)2–H 2 O bulk electrolyte. The MOF encapsulated Zn(TFSI)2‐TFEP forms a ZnF 2‐Zn 3(PO 4)2 solid electrolyte interphase (SEI) preventing Zn dendrite and water decomposition. The Zn(TFSI)2‐TFEP@MOF electrolyte protected Zn anode enables a Zn||Ti cell to achieve a high average Coulombic efficiency of 99.1 % for 350 cycles. The highly reversible Zn anode brings a high energy density of 210 Wh kg−1 (of cathode and anode mass) and a low capacity decay rate of 0.0047 % per cycle over 600 cycles in a Zn||MnO 2 full cell with a low capacity ratio of Zn:MnO 2 at 2:1.
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Cites
Highly reversible zinc metal anode for aqueous batteries
Wang, F., Borodin, O., Gao, T., Fan, X., Sun, W., Han, F., Faraone, A., Dura, J. A., Xu, K., & Wang, C. (2018) · Nature Materials · doi:10.1038/s41563-018-0063-z · Cited by 3,305
Self-citationScientific Challenges for the Implementation of Zn-Ion Batteries
Blanc, L. E., Kundu, D., & Nazar, L. F. (2020) · Joule · doi:10.1016/j.joule.2020.03.002 · Cited by 2,113
Zn/MnO2 Battery Chemistry With H+ and Zn2+ Coinsertion
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Self-citationMetal–organic framework-based separator for lithium–sulfur batteries
Bai, S., Liu, X., Zhu, K., Wu, S., & Zhou, H. (2016) · Nature Energy · doi:10.1038/nenergy.2016.94 · Cited by 1,333
Tunable Electrical Conductivity in Metal-Organic Framework Thin-Film Devices
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A flexible rechargeable aqueous zinc manganese-dioxide battery working at −20 °C
Mo, F., Liang, G., Meng, Q., Liu, Z., Li, H., Fan, J., & Zhi, C. (2019) · Energy & Environmental Science · doi:10.1039/c8ee02892c · Cited by 687
Hydrogen‐Free and Dendrite‐Free All‐Solid‐State Zn‐Ion Batteries
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Reverse Dual-Ion Battery via a ZnCl2 Water-in-Salt Electrolyte
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Li, M., Li, Z., Wang, X., Meng, J., Liu, X., Wu, B., Han, C., & Mai, L. (2021) · Energy & Environmental Science · doi:10.1039/d1ee00030f · Cited by 559
Zeng, X., Xie, K., Liu, S., Zhang, S., Hao, J., Liu, J., Pang, W. K., Liu, J., Rao, P., Wang, Q., et al. (2021) · Energy & Environmental Science · doi:10.1039/d1ee01851e · Cited by 528
Insight on Organic Molecules in Aqueous Zn‐Ion Batteries with an Emphasis on the Zn Anode Regulation
Wang, D., Li, Q., Zhao, Y., Hong, H., Li, H., Huang, Z., Liang, G., Yang, Q., & Zhi, C. (2022) · Advanced Energy Materials · doi:10.1002/aenm.202102707 · Cited by 478
Self-citationA Double-Functional Additive Containing Nucleophilic Groups for High-Performance Zn-Ion Batteries
Wan, J., Wang, R., Liu, Z., Zhang, L., Liang, F., Zhou, T., Zhang, S., Zhang, L., Lu, Q., Zhang, C., et al. (2023) · ACS Nano · doi:10.1021/acsnano.2c11357 · Cited by 406
Metadata
- Authors
- Cao, L., Li, D., Deng, T., Li, Q., & Wang, C.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2020-08-20
- Volume
- 59
- Issue
- 43
- Pages
- 19292-19296
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W3041449146
- Cited by
- 401
- References
- 15
- FWCI
- 22.36
- Type
- journal article
- Language
- en
- Open access
- closed
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