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Cited by 404

The DOI matches its Crossref record; 28 of the 28 references it cites were found in a registry or an index.

Engineering Janus Interfaces of Ceramic Electrolyte via Distinct Functional Polymers for Stable High-Voltage Li-Metal Batteries

Liang, Jia-Yan, Zeng, Xian-Xiang, Zhang, Xu-Dong, Zuo, Tong-Tong, Yan, Min, Yin, Ya-Xia, Shi, Ji-Lei, Wu, Xiong-Wei, Guo, Yu-Guo, Wan, Li-Jun·2019·Journal of the American Chemical Society

Abstract

Abstract The fast-ionic-conducting ceramic electrolyte is promising for next-generation high-energy-density Li-metal batteries, yet its application suffers from the high interfacial resistance and poor interfacial stability. In this study, the compatible solid-state electrolyte was designed by coating Li1.4Al0.4Ti1.6(PO4)3 (LATP) with polyacrylonitrile (PAN) and polyethylene oxide (PEO) oppositely to satisfy deliberately the disparate interface demands. Wherein, the upper PAN constructs soft-contact with LiNi0.6Mn0.2Co0.2O2, and the lower PEO protects LATP from being reduced, guaranteeing high-voltage tolerance and improved stability toward Li-metal anode performed in one ceramic. Moreover, the core function of LATP is amplified to guide homogeneous ions distribution and hence suppresses the formation of a space-charge layer across interfaces, uncovered by the COMSOL Multiphysics concentration field simulation. Thus, such a bifunctional modified ceramic electrolyte integrates the respective superiority to render Li-metal batteries with excellent cycling stability (89% after 120 cycles), high Coulombic efficiency (exceeding 99.5% per cycle), and a dendrite-free Li anode at 60 °C, which represents an overall design of ceramic interface engineering for future practical solid battery systems.

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Metadata

Authors
Liang, J.-Y., Zeng, X.-X., Zhang, X.-D., Zuo, T.-T., Yan, M., Yin, Y.-X., Shi, J.-L., Wu, X.-W., Guo, Y.-G., & Wan, L.-J.
Venue
Journal of the American Chemical Society
Published
2019-05-29
Volume
141
Issue
23
Pages
9165-9169
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2947661081
Cited by
404
References
28
FWCI
16.65
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Engineering Janus Interfaces of Ceramic Electrolyte via Distinct Functional Polymers for Stable High-Voltage Li-Metal Batteries. https://app.cochat.ai/papers/10.1021/jacs.9b03517
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Liang, J.-Y., Zeng, X.-X., Zhang, X.-D., Zuo, T.-T., Yan, M., Yin, Y.-X., Shi, J.-L., Wu, X.-W., Guo, Y.-G., & Wan, L.-J. (2019). Engineering Janus Interfaces of Ceramic Electrolyte via Distinct Functional Polymers for Stable High-Voltage Li-Metal Batteries. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.9b03517

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