The DOI matches its Crossref record; 28 of the 28 references it cites were found in a registry or an index.
Engineering Janus Interfaces of Ceramic Electrolyte via Distinct Functional Polymers for Stable High-Voltage Li-Metal Batteries
Abstract
Abstract The fast-ionic-conducting ceramic electrolyte is promising for next-generation high-energy-density Li-metal batteries, yet its application suffers from the high interfacial resistance and poor interfacial stability. In this study, the compatible solid-state electrolyte was designed by coating Li1.4Al0.4Ti1.6(PO4)3 (LATP) with polyacrylonitrile (PAN) and polyethylene oxide (PEO) oppositely to satisfy deliberately the disparate interface demands. Wherein, the upper PAN constructs soft-contact with LiNi0.6Mn0.2Co0.2O2, and the lower PEO protects LATP from being reduced, guaranteeing high-voltage tolerance and improved stability toward Li-metal anode performed in one ceramic. Moreover, the core function of LATP is amplified to guide homogeneous ions distribution and hence suppresses the formation of a space-charge layer across interfaces, uncovered by the COMSOL Multiphysics concentration field simulation. Thus, such a bifunctional modified ceramic electrolyte integrates the respective superiority to render Li-metal batteries with excellent cycling stability (89% after 120 cycles), high Coulombic efficiency (exceeding 99.5% per cycle), and a dendrite-free Li anode at 60 °C, which represents an overall design of ceramic interface engineering for future practical solid battery systems.
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Citations
Cites
Reviving the lithium metal anode for high-energy batteries
Lin, D., Liu, Y., & Cui, Y. (2017) · Nature Nanotechnology · doi:10.1038/nnano.2017.16 · Cited by 6,763
A solid future for battery development
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Negating interfacial impedance in garnet-based solid-state Li metal batteries
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Mechanism of Lithium Metal Penetration through Inorganic Solid Electrolytes
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Self-citationPlating a Dendrite-Free Lithium Anode with a Polymer/Ceramic/Polymer Sandwich Electrolyte
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An anion-immobilized composite electrolyte for dendrite-free lithium metal anodes
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Metadata
- Authors
- Liang, J.-Y., Zeng, X.-X., Zhang, X.-D., Zuo, T.-T., Yan, M., Yin, Y.-X., Shi, J.-L., Wu, X.-W., Guo, Y.-G., & Wan, L.-J.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-05-29
- Volume
- 141
- Issue
- 23
- Pages
- 9165-9169
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2947661081
- Cited by
- 404
- References
- 28
- FWCI
- 16.65
- Type
- journal article
- Language
- en
- Open access
- closed
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- Liang, J.-Y., Zeng, X.-X., Zhang, X.-D., Zuo, T.-T., Yan, M., Yin, Y.-X., Shi, J.-L., Wu, X.-W., Guo, Y.-G., & Wan, L.-J. (2019). Engineering Janus Interfaces of Ceramic Electrolyte via Distinct Functional Polymers for Stable High-Voltage Li-Metal Batteries. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.9b03517
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