The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Degradation of NASICON-Type Materials in Contact with Lithium Metal: Formation of Mixed Conducting Interphases (MCI) on Solid Electrolytes
Abstract
We report on the transport properties of lithium ion conducting glass ceramics represented by the general composition Li 1+ x – y Al x 3+ M y 5+ M 2– x – y 4+ (PO 4 ) 3 with NASICON-type structure and their stability in contact with lithium metal. In particular, solid electrolyte phases with M = Ge, M = Ti, Ge, and M = Ti, Ta were investigated. AC impedance spectroscopy and DC polarization measurements were applied to determine the conductivity as a function of temperature, and to extract the partial electronic conductivity. The maximum total conductivity at room temperature was found to be about 4 × 10 –4 S/cm for the solely Ge containing sample. We demonstrate that the combination of vacuum-based lithium thin film deposition and X-ray photoelectron spectroscopy (XPS) is well suited to study the reactivity of the solid electrolyte membranes in contact with lithium. As a major result, we show that none of the materials investigated is stable in contact with lithium metal, and we discuss the reactive interaction between solid electrolytes and Li metal in terms of the formation of a mixed (ionic/electronic) conducting interphase (MCI) following the well-known SEI concept in liquid electrolytes.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Advanced Model for Solid Electrolyte Interphase Electrodes in Liquid and Polymer Electrolytes
Peled, E., Golodnitsky, D., & Ardel, G. (1997) · Journal of The Electrochemical Society · doi:10.1149/1.1837858 · Cited by 1,205
Cited by
Wenzel, S., Randau, S., Leichtweiß, T., Weber, D. A., Sann, J., Zeier, W. G., & Janek, J. (2016) · Chemistry of Materials · doi:10.1021/acs.chemmater.6b00610 · Cited by 854
Self-citationFrom lithium to sodium: Cell chemistry of room temperature sodium–air and sodium–sulfur batteries
Adelhelm, P., Hartmann, P., Bender, C. L., Busche, M., Eufinger, C., & Janek, J. (2015) · Beilstein Journal of Nanotechnology · doi:10.3762/bjnano.6.105 · Cited by 478
Self-citationLiang, J.-Y., Zeng, X.-X., Zhang, X.-D., Zuo, T.-T., Yan, M., Yin, Y.-X., Shi, J.-L., Wu, X.-W., Guo, Y.-G., & Wan, L.-J. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b03517 · Cited by 404
Mobile Ions in Composite Solids
Zou, Z., Li, Y., Lu, Z., Wang, D., Cui, Y., Guo, B., Li, Y., Liang, X., Feng, J., Li, H., et al. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00760 · Cited by 348
Stabilizing the Interface of NASICON Solid Electrolyte against Li Metal with Atomic Layer Deposition
Liu, Y., Sun, Q., Zhao, Y., Wang, B., Kaghazchi, P., Adair, K. R., Li, R., Zhang, C., Liu, J., Kuo, L.-Y., et al. (2018) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.8b06366 · Cited by 312
Metadata
- Authors
- Hartmann, P., Leichtweiss, T., Busche, M. R., Schneider, M., Reich, M., Sann, J., Adelhelm, P., & Janek, J.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-10-03
- Volume
- 117
- Issue
- 41
- Pages
- 21064-21074
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2325105709
- Cited by
- 523
- References
- 1
- FWCI
- 7.19
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Degradation of NASICON-Type Materials in Contact with Lithium Metal: Formation of Mixed Conducting Interphases (MCI) on Solid Electrolytes. https://app.cochat.ai/papers/10.1021/jp4051275
- The paper
- Hartmann, P., Leichtweiss, T., Busche, M. R., Schneider, M., Reich, M., Sann, J., Adelhelm, P., & Janek, J. (2013). Degradation of NASICON-Type Materials in Contact with Lithium Metal: Formation of Mixed Conducting Interphases (MCI) on Solid Electrolytes. The Journal of Physical Chemistry C. https://doi.org/10.1021/jp4051275
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
