The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Early Stages of Electrochemical Oxidation of Cu(111) and Polycrystalline Cu Surfaces Revealed by in Situ Raman Spectroscopy
Abstract
Investigating the chemical nature of the adsorbed intermediate species on well-defined Cu single crystal substrates is crucial in understanding many electrocatalytic reactions. Herein, we systematically study the early stages of electrochemical oxidation of Cu(111) and polycrystalline Cu surfaces in different pH electrolytes using in situ shell-isolated nanoparticle-enhanced Raman spectroscopy (SHINERS). On Cu(111), for the first time, we identified surface OH species which convert to chemisorbed “O” before forming Cu 2 O in alkaline (0.01 M KOH) and neutral (0.1 M Na 2 SO 4 ) electrolytes; while at the Cu(poly) surface, we only detected the presence of surface hydroxide. Whereas, in a strongly acidic solution (0.1 M H 2 SO 4 ), sulfate replaces the hydroxyl/oxy species. This results improves the understanding of the reaction mechanisms of various electrocatalytic reactions.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Surface raman spectroelectrochemistry
Jeanmaire, D. L., & Van Duyne, R. P. (1977) · Journal of Electroanalytical Chemistry and Interfacial Electrochemistry · doi:10.1016/s0022-0728(77)80224-6 · Cited by 4,738
CO 2 electroreduction to ethylene via hydroxide-mediated copper catalysis at an abrupt interface
Dinh, C.-T., Burdyny, T., Kibria, M. G., Seifitokaldani, A., Gabardo, C. M., García de Arquer, F. P., Kiani, A., Edwards, J. P., De Luna, P., Bushuyev, O. S., et al. (2018) · Science · doi:10.1126/science.aas9100 · Cited by 2,515
Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper
Li, C. W., Ciston, J., & Kanan, M. W. (2014) · Nature · doi:10.1038/nature13249 · Cited by 1,728
Is Subsurface Oxygen Necessary for the Electrochemical Reduction of CO 2 on Copper?
Garza, A. J., Bell, A. T., & Head-Gordon, M. (2018) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.7b03180 · Cited by 148
Cited by
Zhan, C., Dattila, F., Rettenmaier, C., Bergmann, A., Kühl, S., García-Muelas, R., López, N., & Cuenya, B. R. (2021) · ACS Catalysis · doi:10.1021/acscatal.1c01478 · Cited by 554
A high-entropy atomic environment converts inactive to active sites for electrocatalysis
Zhu, H., Sun, S., Hao, J., Zhuang, Z., Zhang, S., Wang, T., Kang, Q., Lu, S., Wang, X., Lai, F., et al. (2023) · Energy & Environmental Science · doi:10.1039/d2ee03185j · Cited by 509
Bai, L., Franco, F., Timoshenko, J., Rettenmaier, C., Scholten, F., Jeon, H. S., Yoon, A., Rüscher, M., Herzog, A., Haase, F. T., et al. (2024) · Journal of the American Chemical Society · doi:10.1021/jacs.3c13288 · Cited by 473
An, H., Wu, L., Mandemaker, L. D. B., Yang, S., de Ruiter, J., Wijten, J. H. J., Janssens, J. C. L., Hartman, T., van der Stam, W., & Weckhuysen, B. M. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202104114 · Cited by 353
Zhao, Y., Zhang, X.-G., Bodappa, N., Yang, W.-M., Liang, Q., Radjenovica, P. M., Wang, Y.-H., Zhang, Y.-J., Dong, J.-C., Tian, Z.-Q., et al. (2022) · Energy & Environmental Science · doi:10.1039/d2ee01334g · Cited by 293
Self-citation
Metadata
- Authors
- Bodappa, N., Su, M., Zhao, Y., Le, J.-B., Yang, W.-M., Radjenovic, P., Dong, J.-C., Cheng, J., Tian, Z.-Q., & Li, J.-F.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-07-21
- Volume
- 141
- Issue
- 31
- Pages
- 12192-12196
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2963324608
- Cited by
- 274
- References
- 4
- FWCI
- 4.59
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Early Stages of Electrochemical Oxidation of Cu(111) and Polycrystalline Cu Surfaces Revealed by in Situ Raman Spectroscopy. https://app.cochat.ai/papers/10.1021/jacs.9b04638
- The paper
- Bodappa, N., Su, M., Zhao, Y., Le, J.-B., Yang, W.-M., Radjenovic, P., Dong, J.-C., Cheng, J., Tian, Z.-Q., & Li, J.-F. (2019). Early Stages of Electrochemical Oxidation of Cu(111) and Polycrystalline Cu Surfaces Revealed by in Situ Raman Spectroscopy. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.9b04638
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
