The DOI matches its Crossref record; 29 of the 29 references it cites were found in a registry or an index.
Regulating the Inner Helmholtz Plane for Stable Solid Electrolyte Interphase on Lithium Metal Anodes
Abstract
Abstract The stability of a battery is strongly dependent on the feature of solid electrolyte interphase (SEI). The electrical double layer forms prior to the formation of SEI at the interface between the Li metal anode and the electrolyte. The fundamental understanding on the regulation of the SEI structure and stability on Li surface through the structure of the electrical double layer is highly necessary for safe batteries. Herein, the interfacial chemistry of the SEI is correlated with the initial Li surface adsorption electrical double layer at the nanoscale through theoretical and experimental analysis. Under the premise of the constant solvation sheath structure of Li+ in bulk electrolyte, a trace amount of lithium nitrate (LiNO3) and copper fluoride (CuF2) were employed in electrolytes to build robust electric double layer structures on a Li metal surface. The distinct results were achieved with the initial competitive adsorption of bis(fluorosulfonyl)imide ion (FSI–), fluoride ion (F–), and nitrate ion (NO3–) in the inner Helmholtz plane. As a result, Cu–NO3– complexes are preferentially adsorbed and reduced to form the SEI. The modified Li metal electrode can achieve an average Coulombic efficiency of 99.5% over 500 cycles, enabling a long lifespan and high capacity retention of practical rechargeable batteries. The as-proposed mechanism bridges the gap between Li+ solvation and the adsorption about the electrode interface formation in a working battery.
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Cited by
Lithium Batteries and the Solid Electrolyte Interphase (SEI)—Progress and Outlook
Adenusi, H., Chass, G. A., Passerini, S., Tian, K. V., & Chen, G. (2023) · Advanced Energy Materials · doi:10.1002/aenm.202203307 · Cited by 830
Liu, W., Liu, P., & Mitlin, D. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202002297 · Cited by 687
Emerging Era of Electrolyte Solvation Structure and Interfacial Model in Batteries
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Insight on Organic Molecules in Aqueous Zn‐Ion Batteries with an Emphasis on the Zn Anode Regulation
Wang, D., Li, Q., Zhao, Y., Hong, H., Li, H., Huang, Z., Liang, G., Yang, Q., & Zhi, C. (2022) · Advanced Energy Materials · doi:10.1002/aenm.202102707 · Cited by 478
Self-citationRecent Advances in Heterostructure Engineering for Lithium–Sulfur Batteries
Huang, S., Wang, Z., Von Lim, Y., Wang, Y., Li, Y., Zhang, D., & Yang, H. Y. (2021) · Advanced Energy Materials · doi:10.1002/aenm.202003689 · Cited by 438
Metadata
- Authors
- Yan, C., Li, H.-R., Chen, X., Zhang, X.-Q., Cheng, X.-B., Xu, R., Huang, J.-Q., & Zhang, Q.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-05-22
- Volume
- 141
- Issue
- 23
- Pages
- 9422-9429
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2947355882
- Cited by
- 769
- References
- 29
- FWCI
- 23.35
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yan, C., Li, H.-R., Chen, X., Zhang, X.-Q., Cheng, X.-B., Xu, R., Huang, J.-Q., & Zhang, Q. (2019). Regulating the Inner Helmholtz Plane for Stable Solid Electrolyte Interphase on Lithium Metal Anodes. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.9b05029
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