The DOI matches its Crossref record; 45 of the 45 references it cites were found in a registry or an index.
Mechanism of Photocatalytic CO2 Reduction by Bismuth-Based Perovskite Nanocrystals at the Gas–Solid Interface
Abstract
We report here a series of nontoxic and stable bismuth-based perovskite nanocrystals (PeNCs) with applications for photocatalytic reduction of carbon dioxide to methane and carbon monoxide. Three bismuth-based PeNCs of general chemical formulas A 3 Bi 2 I 9, in which cation A + = Rb + or Cs + or CH 3 NH 3 + (MA + ), were synthesized with a novel ultrasonication top-down method. PeNC of Cs 3 Bi 2 I 9 had the best photocatalytic activity for the reduction of CO 2 at the gas–solid interface with formation yields 14.9 μmol g –1 of methane and 77.6 μmol g –1 of CO, representing a much more effective catalyst than TiO 2 (P25) under the same experimental conditions. The products of the photocatalytic reactions were analyzed using a gas chromatograph coupled with a mass spectrometer. According to electron paramagnetic resonance and diffuse-reflectance infrared spectra, we propose a reaction mechanism for photoreduction of CO 2 via Bi-based PeNC photocatalysts to form CO, CH 4, and other possible side products.
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Bright light-emitting diodes based on organometal halide perovskite
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Photocatalytic Reduction of CO2 on TiO2 and Other Semiconductors
Habisreutinger, S. N., Schmidt‐Mende, L., & Stolarczyk, J. K. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201207199 · Cited by 2,989
Overcoming the electroluminescence efficiency limitations of perovskite light-emitting diodes
Cho, H., Jeong, S.-H., Park, M.-H., Kim, Y.-H., Wolf, C., Lee, C.-L., Heo, J. H., Sadhanala, A., Myoung, N., Yoo, S., et al. (2015) · Science · doi:10.1126/science.aad1818 · Cited by 2,925
CO2 photo-reduction: insights into CO2 activation and reaction on surfaces of photocatalysts
Chang, X., Wang, T., & Gong, J. (2016) · Energy & Environmental Science · doi:10.1039/c6ee00383d · Cited by 2,018
Enhanced Photocatalytic CO2-Reduction Activity of Anatase TiO2 by Coexposed {001} and {101} Facets
Yu, J., Low, J., Xiao, W., Zhou, P., & Jaroniec, M. (2014) · Journal of the American Chemical Society · doi:10.1021/ja5044787 · Cited by 1,905
Efficient perovskite light-emitting diodes featuring nanometre-sized crystallites
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Nontemplate Synthesis of CH3NH3PbBr3 Perovskite Nanoparticles
Schmidt, L. C., Pertegás, A., González-Carrero, S., Malinkiewicz, O., Agouram, S., Mínguez Espallargas, G., Bolink, H. J., Galian, R. E., & Pérez-Prieto, J. (2014) · Journal of the American Chemical Society · doi:10.1021/ja4109209 · Cited by 1,327
Bismuth Based Hybrid Perovskites A3Bi2I9 (A: Methylammonium or Cesium) for Solar Cell Application
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A CsPbBr3 Perovskite Quantum Dot/Graphene Oxide Composite for Photocatalytic CO2 Reduction
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Cited by
Sheng, J., He, Y., Li, J., Yuan, C., Huang, H., Wang, S., Sun, Y., Wang, Z., & Dong, F. (2020) · ACS Nano · doi:10.1021/acsnano.0c04659 · Cited by 522
Metadata
- Authors
- Bhosale, S. S., Kharade, A. K., Jokar, E., Fathi, A., Chang, S.-M., & Diau, E. W.-G.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-12-04
- Volume
- 141
- Issue
- 51
- Pages
- 20434-20442
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2991968401
- Cited by
- 268
- References
- 45
- FWCI
- 6.49
- Type
- journal article
- Language
- en
- Open access
- closed
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- Bhosale, S. S., Kharade, A. K., Jokar, E., Fathi, A., Chang, S.-M., & Diau, E. W.-G. (2019). Mechanism of Photocatalytic CO2 Reduction by Bismuth-Based Perovskite Nanocrystals at the Gas–Solid Interface. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.9b11089
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