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Mechanism of Photocatalytic CO2 Reduction by Bismuth-Based Perovskite Nanocrystals at the Gas–Solid Interface
Abstract
We report here a series of nontoxic and stable bismuth-based perovskite nanocrystals (PeNCs) with applications for photocatalytic reduction of carbon dioxide to methane and carbon monoxide. Three bismuth-based PeNCs of general chemical formulas A 3 Bi 2 I 9, in which cation A + = Rb + or Cs + or CH 3 NH 3 + (MA + ), were synthesized with a novel ultrasonication top-down method. PeNC of Cs 3 Bi 2 I 9 had the best photocatalytic activity for the reduction of CO 2 at the gas–solid interface with formation yields 14.9 μmol g –1 of methane and 77.6 μmol g –1 of CO, representing a much more effective catalyst than TiO 2 (P25) under the same experimental conditions. The products of the photocatalytic reactions were analyzed using a gas chromatograph coupled with a mass spectrometer. According to electron paramagnetic resonance and diffuse-reflectance infrared spectra, we propose a reaction mechanism for photoreduction of CO 2 via Bi-based PeNC photocatalysts to form CO, CH 4, and other possible side products.
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Metadata
- Authors
- Bhosale, S. S., Kharade, A. K., Jokar, E., Fathi, A., Chang, S.-M., & Diau, E. W.-G.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-12-04
- Volume
- 141
- Issue
- 51
- Pages
- 20434-20442
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2991968401
- Cited by
- 268
- References
- 45
- FWCI
- 6.49
- Type
- journal article
- Language
- en
- Open access
- closed
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