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Effect of Water on the Density, Viscosity, and CO2 Solubility in Choline Chloride/Urea
Open accessAbstract
To study the effect of water on the properties of choline chloride (ChCl)/urea mixtures (1:2 on a molar basis), the density and viscosity of ChCl/urea (1:2) with water were measured at temperatures from 298.15 K to 333.15 K at atmospheric pressure, the CO 2 solubility in ChCl/urea (1:2) with water was determined at 308.2 K, 318.2 K, and 328.2 K and at pressures up to 4.5 MPa. The results show that the addition of water significantly decreases the viscosity of ChCl/urea (1:2), whereas the effects on their density and CO 2 solubility are much weaker. The CO 2 solubility in ChCl/urea (1:2) with water was represented with the Nonrandom-Two-Liquid Redlich–Kwong (NRTL-RK) model. The excess molar volume and excess molar activation energy were further determined. The CO 2 absorption enthalpy was calculated and dominated by the CO 2 dissolution enthalpy, and the magnitude of the CO 2 dissolution enthalpy decreases with the increase of water content.
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Cites
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Influence of chloride, water, and organic solvents on the physical properties of ionic liquids
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A Review of CO2 Capture by Absorption and Adsorption
Yu, C.-H., Huang, C.-H., & Tan, C.-S. (2012) · Aerosol and Air Quality Research · doi:10.4209/aaqr.2012.05.0132 · Cited by 1,730
Cited by
The peculiar effect of water on ionic liquids and deep eutectic solvents
Ma, C., Laaksonen, A., Liu, C., Lu, X., & Ji, X. (2018) · Chemical Society Reviews · doi:10.1039/c8cs00325d · Cited by 584
Self-citationCarbon Dioxide Capture with Ionic Liquids and Deep Eutectic Solvents: A New Generation of Sorbents
Sarmad, S., Mikkola, J., & Ji, X. (2017) · ChemSusChem · doi:10.1002/cssc.201600987 · Cited by 406
Self-citationFlorindo, C., Romero, L., Rintoul, I., Branco, L. C., & Marrucho, I. M. (2018) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.7b04235 · Cited by 389
Ge, X., Gu, C., Wang, X., & Tu, J. (2017) · Journal of Materials Chemistry A · doi:10.1039/c7ta01659j · Cited by 372
Emerging technologies for the production of nanocellulose from lignocellulosic biomass
Pradhan, D., Jaiswal, A. K., & Jaiswal, S. (2022) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2022.119258 · Cited by 294
Metadata
- Authors
- Xie, Y., Dong, H., Zhang, S., Lu, X., & Ji, X.
- Venue
- Journal of Chemical & Engineering Data
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-11-04
- Volume
- 59
- Issue
- 11
- Pages
- 3344-3352
- ISSN
- 0021-9568 (ISSN-L)
- 1520-5134
- OpenAlex
- W2323590840
- Cited by
- 219
- References
- 5
- FWCI
- 3.12
- Type
- journal article
- Language
- en
- Open access
- green
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