The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Binding of Fluoroquinolone Carboxylic Acid Derivatives to Clay Minerals
Abstract
Large quantities of fluoroquinolone carboxylic acid (FQCA) derivatives are applied as antibacterial agents in large-scale animal husbandry. Important quantities are transported to agricultural areas by means of liquid manure. The binding of FQCA derivatives to clay minerals and their sorption by five soils from different geographic areas were investigated. Sorption was studied in batch experiments using radioactive labeled enrofloxacin (Baytril), decarboxylated enrofloxacin, ciprofloxacin (Cyprobay), levofloxacin (Oxaldin), and a fluorochloroquinolone carboxylic acid derivative. More than 90% ( K D = 260−5612) of the applied enrofloxacin adsorbed on the different soils. The other chemicals showed a similar adsorption ( K D = 285−496) on a German soil except the decarboxylated enrofloxacin ( K D = 7.7). At clay minerals enrofloxacin was adsorbed >98%. X-ray diffraction analysis showed that the adsorption at the clay mineral montmorillonite occurred between the layers, resulting in an expansion of the spacing. Microcalorimetric and infrared measurements confirmed an electrostatic interaction between the adsorbed chemical and the adsorbent. Keywords: Adsorption; clay mineral; enrofloxacin; fluoroquinolone carboxylic acid derivatives; Coulombic interactions; soil clays
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Citations
Cites
Mortland, M. M. (1975) · Soil Science Society of America Journal · doi:10.2136/sssaj1975.03615995003900020002x · Cited by 1,154
Environmental organic chemistry
Wangersky, P. J. (1994) · Journal of Contaminant Hydrology · doi:10.1016/0169-7722(94)90027-2 · Cited by 905
Haider, K. (1992) · Earth-Science Reviews · doi:10.1016/0012-8252(92)90039-v · Cited by 252
Bakker, H. (1970) · Geoderma · doi:10.1016/0016-7061(70)90045-5 · Cited by 43
Cited by
Sarmah, A. K., Meyer, M. T., & Boxall, A. B. A. (2006) · Chemosphere · doi:10.1016/j.chemosphere.2006.03.026 · Cited by 3,326
Fluoroquinolone antibiotics: An emerging class of environmental micropollutants
Van Doorslaer, X., Dewulf, J., Van Langenhove, H., & Demeestere, K. (2014) · Science of The Total Environment · doi:10.1016/j.scitotenv.2014.08.075 · Cited by 819
Modeling Tetracycline Antibiotic Sorption to Clays
Figueroa, R. A., Leonard, A., & MacKay, A. A. (2004) · Environmental Science & Technology · doi:10.1021/es0342087 · Cited by 621
Toxicity of fluoroquinolone antibiotics to aquatic organisms
Robinson, A. A., Belden, J. B., & Lydy, M. J. (2005) · Environmental Toxicology and Chemistry · doi:10.1897/04-210r.1 · Cited by 512
Occurrence and Fate of Human Pharmaceuticals in the Environment
Monteiro, S. C., & Boxall, A. B. A. (2010) · Reviews of Environmental Contamination and Toxicology · doi:10.1007/978-1-4419-1157-5_2 · Cited by 451
Metadata
- Authors
- Nowara, A., Burhenne, J., & Spiteller, M.
- Venue
- Journal of Agricultural and Food Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 1997-04-01
- Volume
- 45
- Issue
- 4
- Pages
- 1459-1463
- ISSN
- 0021-8561 (ISSN-L)
- 1520-5118
- OpenAlex
- W2089979285
- Cited by
- 288
- References
- 4
- FWCI
- 4.25
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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