The DOI matches its Crossref record; 25 of the 25 references it cites were found in a registry or an index.
Effect of the Solvent Environment on the Spectroscopic Properties and Dynamics of the Lowest Excited States of Carotenoids
Abstract
The spectroscopic properties and dynamics of the lowest excited singlet states of peridinin, fucoxanthin, neoxanthin, uriolide acetate, spheroidene, and spheroidenone in several different solvents have been studied by steady-state absorption and fast-transient optical spectroscopic techniques. Peridinin, fucoxanthin, uriolide acetate, and spheroidenone, which contain carbonyl functional groups in conjugation with the carbon−carbon π-electron system, display broader absorption spectral features and are affected more by the solvent environment than neoxanthin and spheroidene, which do not contain carbonyl functional groups. The possible sources of the spectral broadening are explored by examining the absorption spectra at 77 K in glassy solvents. Also, carotenoids which contain carbonyls have complex transient absorption spectra and show a pronounced dependence of the excited singlet state lifetime on the solvent environment. It is postulated that these effects are related to the presence of an intramolecular charge transfer state strongly coupled to the S 1 (2 1 A g ) excited singlet state. Structural variations in the series of carotenoids studied here make it possible to focus on the general molecular features that control the spectroscopic and dynamic properties of carotenoids.
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Cites
Principles of Fluorescence Spectroscopy
Lakowicz, J. R. (1999) · Springer eBooks · doi:10.1007/978-1-4757-3061-6 · Cited by 26,947
Principles of Fluorescence Spectroscopy
Lakowicz, J. R. (1983) · Springer eBooks · doi:10.1007/978-1-4615-7658-7 · Cited by 5,014
Relationship between Absorption Intensity and Fluorescence Lifetime of Molecules
Strickler, S. J., & Berg, R. A. (1962) · The Journal of Chemical Physics · doi:10.1063/1.1733166 · Cited by 2,481
Rettig, W. (1986) · Angewandte Chemie International Edition in English · doi:10.1002/anie.198609711 · Cited by 1,324
Frank, H. A., & Cogdell, R. J. (1996) · Photochemistry and Photobiology · doi:10.1111/j.1751-1097.1996.tb03022.x · Cited by 1,184
Self-citationThe Biochemistry of the Carotenoids
Goodwin, T. W. (1984) · Springer eBooks · doi:10.1007/978-94-009-5542-4 · Cited by 1,007
The Photochemistry of Carotenoids
(1999) · Advances in Photosynthesis and Respiration · doi:10.1007/0-306-48209-6 · Cited by 769
Hofmann, E., Wrench, P. M., Sharples, F. P., Hiller, R. G., Welte, W., & Diederichs, K. (1996) · Science · doi:10.1126/science.272.5269.1788 · Cited by 465
Self-citationHow carotenoids function in photosynthetic bacteria
Cogdell, R. J., & Frank, H. A. (1987) · Biochimica et Biophysica Acta (BBA) - Reviews on Bioenergetics · doi:10.1016/s0304-4173(87)80008-3 · Cited by 462
Self-citationPhotophysics of the carotenoids associated with the xanthophyll cycle in photosynthesis
Frank, H. A., Cua, A., Chynwat, V., Young, A., Gosztola, D., & Wasielewski, M. R. (1994) · Photosynthesis Research · doi:10.1007/bf02183041 · Cited by 393
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Ultrafast Dynamics of Carotenoid Excited States−From Solution to Natural and Artificial Systems
Polívka, T., & Sundström, V. (2004) · Chemical Reviews · doi:10.1021/cr020674n · Cited by 889
Kosumi, D., Fujii, R., Sugisaki, M., Oka, N., Iha, M., & Hashimoto, H. (2014) · Photosynthesis Research · doi:10.1007/s11120-014-9995-6 · Cited by 22
Metadata
- Authors
- Frank, H. A., Bautista, J. A., Josue, J., Pendon, Z., Hiller, R. G., Sharples, F. P., Gosztola, D., & Wasielewski, M. R.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2000-04-04
- Volume
- 104
- Issue
- 18
- Pages
- 4569-4577
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W1981353021
- Cited by
- 311
- References
- 25
- FWCI
- 8.41
- Type
- journal article
- Language
- en
- Open access
- closed
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- Frank, H. A., Bautista, J. A., Josue, J., Pendon, Z., Hiller, R. G., Sharples, F. P., Gosztola, D., & Wasielewski, M. R. (2000). Effect of the Solvent Environment on the Spectroscopic Properties and Dynamics of the Lowest Excited States of Carotenoids. The Journal of Physical Chemistry B. https://doi.org/10.1021/jp000079u
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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