The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
How To Make Electrocatalysts More Active for Direct Methanol OxidationAvoid PtRu Bimetallic Alloys!
Abstract
Contrary to the current understanding of Pt−Ru electrocatalyzed oxidation of methanol, the bimetallic alloy is not the most desired form of the catalyst. In the nanoscale Pt−Ru blacks used to electrooxidize methanol in direct methanol fuel cells, Pt 0 Ru 0 has orders of magnitude less activity for methanol oxidation than does a mixed-phase electrocatalyst containing Pt metal and hydrous ruthenium oxides (RuO x H y ). Bulk, rather than near-surface, quantities of electron−proton conducting RuO x H y are required to achieve high activity for methanol oxidation. The active catalyst forms a nanoscopic, phase-separated hydrons oxide-on-metal structure that retains the Pt metal−RuO x H y boundaries required to oxidize methanol fully to carbon dioxide and water.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Methanol oxidation and direct methanol fuel cells: a selective review
Wasmus, S., & Küver, A. (1999) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(98)00197-1 · Cited by 1,308
Cited by
Chemistry and Properties of Nanocrystals of Different Shapes
Burda, C., Chen, X., Narayanan, R., & El-Sayed, M. A. (2005) · Chemical Reviews · doi:10.1021/cr030063a · Cited by 7,230
Narayanan, R., & El-Sayed, M. A. (2005) · The Journal of Physical Chemistry B · doi:10.1021/jp051066p · Cited by 1,298
Carbon supports for low-temperature fuel cell catalysts
Antolini, E. (2009) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2008.09.030 · Cited by 1,295
Support materials for PEMFC and DMFC electrocatalysts—A review
Sharma, S., & Pollet, B. G. (2012) · Journal of Power Sources · doi:10.1016/j.jpowsour.2012.02.011 · Cited by 1,206
Catalytic nanoarchitectures—The importance of nothing and the unimportance of periodicity
Rolison, D. R. (2003) · Science · doi:10.1126/science.1082332 · Cited by 1,037
Self-citationZhang, Z., Liu, J., Gu, J., Su, L., & Cheng, L. (2014) · Energy Environ. Sci. · doi:10.1039/c3ee43886d · Cited by 478
Developments of electric cars and fuel cell hydrogen electric cars
Wilberforce, T., El-Hassan, Z., Khatib, F. N., Al Makky, A., Baroutaji, A., Carton, J. G., & Olabi, A. G. (2017) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2017.07.054 · Cited by 478
Developments in fuel cell technologies in the transport sector
Alaswad, A., Baroutaji, A., Achour, H., Carton, J., Al Makky, A., & Olabi, A. G. (2016) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2016.03.164 · Cited by 378
Nanostructured catalysts in fuel cells
Zhong, C.-J., Luo, J., Fang, B., Wanjala, B. N., Njoki, P. N., Loukrakpam, R., & Yin, J. (2010) · Nanotechnology · doi:10.1088/0957-4484/21/6/062001 · Cited by 198
Park, K. C., Jang, I. Y., Wongwiriyapan, W., Morimoto, S., Kim, Y. J., Jung, Y. C., Toya, T., & Endo, M. (2010) · Journal of Materials Chemistry · doi:10.1039/b923153f · Cited by 66
Metadata
- Authors
- Long, J. W., Stroud, R. M., Swider-Lyons, K. E., & Rolison, D. R.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2000-10-01
- Volume
- 104
- Issue
- 42
- Pages
- 9772-9776
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2044383916
- Cited by
- 347
- References
- 1
- FWCI
- 16.31
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
