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Cited by 290

The DOI matches its Crossref record; 42 of the 42 references it cites were found in a registry or an index.

An Extremely Small Reorganization Energy of Electron Transfer in Porphyrin−Fullerene Dyad

Imahori, Hiroshi, Tkachenko, Nikolai V., Vehmanen, Visa, Tamaki, Koichi, Lemmetyinen, Helge, Sakata, Yoshiteru, Fukuzumi, Shunichi·2001·The Journal of Physical Chemistry A
DOI 10.1021/jp003207n
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Abstract

Both charge-transfer absorption and emission have been observed in porphyrin-linked fullerene where the C 60 moiety is closely located on the porphyrin plane. Electron-transfer parameters including reorganization energies, free energy changes, and electronic coupling matrix elements were determined by analyzing the charge-transfer absorption and emission in benzene. The reorganization energy is estimated as 0.23 ± 0.11 eV, which is the smallest value among inter- and intramolecular donor−acceptor systems ever reported and is comparable to the smallest ones for the primary charge separation in the photosynthetic reaction center. The results clearly show that fullerenes combined with porphyrins are potential components for constructing artificial photosynthetic systems.

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Metadata

Authors
Imahori, H., Tkachenko, N. V., Vehmanen, V., Tamaki, K., Lemmetyinen, H., Sakata, Y., & Fukuzumi, S.
Venue
The Journal of Physical Chemistry A
Publisher
American Chemical Society (ACS)
Published
2001-02-10
Volume
105
Issue
10
Pages
1750-1756
ISSN
  • 1089-5639 (ISSN-L)
  • 1520-5215
DOI
10.1021/jp003207n
OpenAlex
W2028416984
Cited by
290
References
42
FWCI
13.37
Type
journal article
Language
en
Open access
closed

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