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New Photocatalyst Group for Water Decomposition of RuO2-Loaded p-Block Metal (In, Sn, and Sb) Oxides with d10 Configuration
Abstract
For the decomposition of pure water to hydrogen and oxygen, MIn 2 O 4 (M = Ca, Sr), Sr 2 SnO 4, and NaSbO 3 were found to make stable photocatalysts when combined with RuO 2 . The metal oxides are composed of the d 10 p-block metal ions (In 3+, Sn 4+, and Sb 5+ ), and it is demonstrated that the p-block metal oxides with d 10 configuration form a new photocatalyst group different from the conventional metal oxide photocatalyst group consisting of the octahedrally coordinated d 0 transition-metal ions such as Ti 4+, Zr 4+, Nb 5+, and Ta 5+ .
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Citations
Cited by
Semiconductor-based Photocatalytic Hydrogen Generation
Chen, X., Shen, S., Guo, L., & Mao, S. S. (2010) · Chemical Reviews · doi:10.1021/cr1001645 · Cited by 7,876
Abe, R. (2010) · Journal of Photochemistry and Photobiology C: Photochemistry Reviews · doi:10.1016/j.jphotochemrev.2011.02.003 · Cited by 1,223
Maeda, K., Teramura, K., Lu, D., Saito, N., Inoue, Y., & Domen, K. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200602473 · Cited by 641
Self-citationInoue, Y. (2009) · Energy & Environmental Science · doi:10.1039/b816677n · Cited by 522
Self-citationPhotocatalytic Activity for Water Decomposition of RuO2-Dispersed Zn2GeO4 with d10 Configuration
Sato, J., Kobayashi, H., Ikarashi, K., Saito, N., Nishiyama, H., & Inoue, Y. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp0373189 · Cited by 320
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Metadata
- Authors
- Sato, J., Saito, N., Nishiyama, H., & Inoue, Y.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2001-06-13
- Volume
- 105
- Issue
- 26
- Pages
- 6061-6063
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2007598092
- Cited by
- 213
- References
- 0
- FWCI
- 5.52
- Type
- journal article
- Language
- en
- Open access
- closed
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- Sato, J., Saito, N., Nishiyama, H., & Inoue, Y. (2001). New Photocatalyst Group for Water Decomposition of RuO2-Loaded p-Block Metal (In, Sn, and Sb) Oxides with d10 Configuration. The Journal of Physical Chemistry B. https://doi.org/10.1021/jp010794j
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