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A Microscopic and Spectroscopic Study of Interactions between Carbon Nanotubes and a Conjugated Polymer
Abstract
Production of stable polymer−nanotube composites depends on good wetting interaction between polymer and nanotube, which is polymer specific, and depends in particular on chain conformation. In this paper, we examine this interaction for a conjugated, semiconducting polymer by a range of microscopic and spectroscopic techniques, to gain a greater understanding of the binding. Several interesting effects are observed, including an order to the interaction between the polymer and nanotube, the tendency of defects in the nanotube structure to nucleate crystal growth, and substantial changes in the spectroscopic behavior of the polymer due to the effect of the nanotubes on polymer conformation. This is substantiated by computational modeling, which demonstrates that these conformational modifications are due to the interaction with the nanotubes.
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Citations
Cited by
Mechanical Reinforcement of Polymers Using Carbon Nanotubes
Coleman, J. N., Khan, U., & Gun'ko, Y. K. (2006) · Advanced Materials · doi:10.1002/adma.200501851 · Cited by 1,621
Self-citationBig returns from small fibers: A review of polymer/carbon nanotube composites
Breuer, O., & Sundararaj, U. (2004) · Polymer Composites · doi:10.1002/pc.20058 · Cited by 1,246
Recent Advances in Research on Carbon Nanotube–Polymer Composites
Byrne, M. T., & Gun'ko, Y. K. (2010) · Advanced Materials · doi:10.1002/adma.200901545 · Cited by 873
Recognition Ability of DNA for Carbon Nanotubes Correlates with Their Binding Affinity
Roxbury, D., Tu, X., Zheng, M., & Jagota, A. (2011) · Langmuir · doi:10.1021/la2007793 · Cited by 104
Structural Characteristics of Oligomeric DNA Strands Adsorbed onto Single-Walled Carbon Nanotubes
Roxbury, D., Jagota, A., & Mittal, J. (2013) · The Journal of Physical Chemistry B · doi:10.1021/jp309523a · Cited by 59
Metadata
- Authors
- McCarthy, B., Coleman, J. N., Czerw, R., Dalton, A. B., in het Panhuis, M., Maiti, A., Drury, A., Bernier, P., Nagy, J. B., Lahr, B., Byrne, H. J., Carroll, D. L., & Blau, W. J.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2002-02-08
- Volume
- 106
- Issue
- 9
- Pages
- 2210-2216
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2077561850
- Cited by
- 237
- References
- 0
- FWCI
- 13.10
- Type
- journal article
- Language
- en
- Open access
- closed
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- McCarthy, B., Coleman, J. N., Czerw, R., Dalton, A. B., in het Panhuis, M., Maiti, A., Drury, A., Bernier, P., Nagy, J. B., Lahr, B., Byrne, H. J., Carroll, D. L., & Blau, W. J. (2002). A Microscopic and Spectroscopic Study of Interactions between Carbon Nanotubes and a Conjugated Polymer. The Journal of Physical Chemistry B. https://doi.org/10.1021/jp013745f
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