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Reduced Symmetry Metallodielectric Nanoparticles: Chemical Synthesis and Plasmonic Properties
Abstract
We report a general chemical strategy for producing reduced-symmetry metallodielectric nanoparticles, nanocups, and nanocaps that combines nanoscale masking techniques and nanoparticle-seeded electroless plating. Using this approach, silica nanoparticles with a gold cup-shaped shell and, alternatively, a gold cap, are obtained. The plasmon response of both nanostructures is a sensitive function of orientation of the nanostructure with respect to the direction and polarization of incident light. This orientation dependence is examined experimentally by studying the extinction spectra of oriented nanocups and nanocaps on transparent substrates, and is also evaluated theoretically using a three-dimensional finite difference time domain (FDTD) method.
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Cited by
Gold nanostructures: engineering their plasmonic properties for biomedical applications
Hu, M., Chen, J., Li, Z.-Y., Au, L., Hartland, G. V., Li, X., Marquez, M., & Xia, Y. (2006) · Chemical Society Reviews · doi:10.1039/b517615h · Cited by 1,756
Gold Nanomaterials at Work in Biomedicine
Yang, X., Yang, M., Pang, B., Vara, M., & Xia, Y. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00193 · Cited by 1,162
Templated Techniques for the Synthesis and Assembly of Plasmonic Nanostructures
Jones, M. R., Osberg, K. D., Macfarlane, R. J., Langille, M. R., & Mirkin, C. A. (2011) · Chemical Reviews · doi:10.1021/cr1004452 · Cited by 1,159
The plasmon band in noble metal nanoparticles: an introduction to theory and applications
Moores, A., & Goettmann, F. (2006) · New Journal of Chemistry · doi:10.1039/b604038c · Cited by 665
Fabrication, Assembly, and Application of Patchy Particles
Pawar, A. B., & Kretzschmar, I. (2010) · Macromolecular Rapid Communications · doi:10.1002/marc.200900614 · Cited by 567
Lu, Y., Liu, G. L., Kim, J., Mejia, Y. X., & Lee, L. P. (2005) · Nano Letters · doi:10.1021/nl048232+ · Cited by 440
Synthesis and Optical Properties of Anisotropic Metal Nanoparticles
Hao, E., Schatz, G. C., & Hupp, J. T. (2004) · Journal of Fluorescence · doi:10.1023/b:jofl.0000031815.71450.74 · Cited by 312
Optical Properties of Metal Nanoshells
Hao, E., Li, S., Bailey, R. C., Zou, S., Schatz, G. C., & Hupp, J. T. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp036301n · Cited by 288
Li, X., Wu, Y., Hang, L., Men, D., Cai, W., & Li, Y. (2015) · Journal of Materials Chemistry C · doi:10.1039/c4tc02228a · Cited by 19
Metadata
- Authors
- Charnay, C., Lee, A., Man, S.-Q., Moran, C. E., Radloff, C., Bradley, R. K., & Halas, N. J.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2003-06-17
- Volume
- 107
- Issue
- 30
- Pages
- 7327-7333
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2088944951
- Cited by
- 174
- References
- 0
- FWCI
- 8.57
- Type
- journal article
- Language
- en
- Open access
- closed
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