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Uniaxial Plasmon Coupling through Longitudinal Self-Assembly of Gold Nanorods
Abstract
We report a new paradigm for tuning the optical properties of gold nanorods by organizing them longitudinally, using thioalkylcarboxylic acid based bifunctional molecules. The rationale behind the selection of the bifunctional molecule is based on the fact that the thiol group binds to the ends of the nanorods, which further assembles in a longitudinal fashion through cooperative hydrogen bonding between the carboxylic groups. A generalized procedure for uniaxial plasmon coupling through longitudinal self-assembly of Au nanorods, initially to dimers and further to linear assemblies, is presented. Uniaxial modulation of interplasmon coupling through stepwise self-assembly of Au nanorods will have application in nanoelectronics and plasmonics.
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Citations
Cited by
Chemistry and Properties of Nanocrystals of Different Shapes
Burda, C., Chen, X., Narayanan, R., & El-Sayed, M. A. (2005) · Chemical Reviews · doi:10.1021/cr030063a · Cited by 7,230
Gold Nanorods: From Synthesis and Properties to Biological and Biomedical Applications
Huang, X., Neretina, S., & El‐Sayed, M. A. (2009) · Advanced Materials · doi:10.1002/adma.200802789 · Cited by 1,921
Tailoring Surface Plasmons through the Morphology and Assembly of Metal Nanoparticles
Liz-Marzán, L. M. (2006) · Langmuir · doi:10.1021/la0513353 · Cited by 1,645
Plasmonic coupling in noble metal nanostructures
Jain, P. K., & El-Sayed, M. A. (2010) · Chemical Physics Letters · doi:10.1016/j.cplett.2010.01.062 · Cited by 963
Self-assembly and applications of anisotropic nanomaterials: A review
Thorkelsson, K., Bai, P., & Xu, T. (2015) · Nano Today · doi:10.1016/j.nantod.2014.12.005 · Cited by 344
Metadata
- Authors
- Thomas, K. G., Barazzouk, S., Ipe, B. I., Joseph, S. T. S., & Kamat, P. V.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2004-05-22
- Volume
- 108
- Issue
- 35
- Pages
- 13066-13068
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2059383474
- Cited by
- 435
- References
- 0
- FWCI
- 16.74
- Type
- journal article
- Language
- en
- Open access
- closed
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- Thomas, K. G., Barazzouk, S., Ipe, B. I., Joseph, S. T. S., & Kamat, P. V. (2004). Uniaxial Plasmon Coupling through Longitudinal Self-Assembly of Gold Nanorods. The Journal of Physical Chemistry B. https://doi.org/10.1021/jp049167v
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