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Uniaxial Plasmon Coupling through Longitudinal Self-Assembly of Gold Nanorods
Abstract
We report a new paradigm for tuning the optical properties of gold nanorods by organizing them longitudinally, using thioalkylcarboxylic acid based bifunctional molecules. The rationale behind the selection of the bifunctional molecule is based on the fact that the thiol group binds to the ends of the nanorods, which further assembles in a longitudinal fashion through cooperative hydrogen bonding between the carboxylic groups. A generalized procedure for uniaxial plasmon coupling through longitudinal self-assembly of Au nanorods, initially to dimers and further to linear assemblies, is presented. Uniaxial modulation of interplasmon coupling through stepwise self-assembly of Au nanorods will have application in nanoelectronics and plasmonics.
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Citations
Cited by
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Halas, N. J., Lal, S., Chang, W.-S., Link, S., & Nordlander, P. (2011) · Chemical Reviews · doi:10.1021/cr200061k · Cited by 3,135
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Nanoscale Forces and Their Uses in Self‐Assembly
Bishop, K. J. M., Wilmer, C. E., Soh, S., & Grzybowski, B. A. (2009) · Small · doi:10.1002/smll.200900358 · Cited by 1,521
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Liao, H., & Hafner, J. H. (2005) · Chemistry of Materials · doi:10.1021/cm050935k · Cited by 434
Silica-Coating and Hydrophobation of CTAB-Stabilized Gold Nanorods
Pastoriza-Santos, I., Pérez-Juste, J., & Liz-Marzán, L. M. (2006) · Chemistry of Materials · doi:10.1021/cm060293g · Cited by 395
Toward functional nanocomposites: taking the best of nanoparticles, polymers, and small molecules
Kao, J., Thorkelsson, K., Bai, P., Rancatore, B. J., & Xu, T. (2013) · Chem. Soc. Rev. · doi:10.1039/c2cs35375j · Cited by 386
Self-assembly and applications of anisotropic nanomaterials: A review
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The Many Faces of Gold Nanorods
Murphy, C. J., Thompson, L. B., Alkilany, A. M., Sisco, P. N., Boulos, S. P., Sivapalan, S. T., Yang, J. A., Chernak, D. J., & Huang, J. (2010) · The Journal of Physical Chemistry Letters · doi:10.1021/jz100992x · Cited by 287
Metadata
- Authors
- Thomas, K. G., Barazzouk, S., Ipe, B. I., Joseph, S. T. S., & Kamat, P. V.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2004-05-22
- Volume
- 108
- Issue
- 35
- Pages
- 13066-13068
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2059383474
- Cited by
- 435
- References
- 0
- FWCI
- 16.74
- Type
- journal article
- Language
- en
- Open access
- closed
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