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Determination of Fracture Energy of High Strength Double Network Hydrogels

Tanaka, Yoshimi, Kuwabara, Rikimaru, Na, Yang-Ho, Kurokawa, Takayuki, Gong, Jian Ping, Osada, Yoshihito·2005·The Journal of Physical Chemistry B

Abstract

The fracture energy G of double network (DN) gels, consisting of poly(2-acrylamido-2-methylpropanesulfonic acid) (PAMPS) as the first network and poly(acrylamide) (PAAm) as the second network, was measured by the tearing test as a function of the crack velocity V. The following results were obtained: (i) The fracture energy G ranges from 10(2) to approximately 10(3) J/m2, which is 100-1000 times larger than that of normal PAAm gels (10(0) J/m2) or PAMPS gels (10(-1) J/m2) with similar polymer concentrations to the DN gels. (ii) G shows weak dependence on the crack velocity V. (iii) G at a given value of V increases with decreasing of cross-linking density of the 2nd network. The measured values of G were compared with three theories that describe different mechanisms enhancing the fracture energy of soft polymeric systems. A mechanism relating to a heterogeneous structure of the DN gel is convincing for the remarkable large values of G.

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Metadata

Authors
Tanaka, Y., Kuwabara, R., Na, Y.-H., Kurokawa, T., Gong, J. P., & Osada, Y.
Venue
The Journal of Physical Chemistry B
Published
2005-05-19
Volume
109
Issue
23
Pages
11559-11562
ISSN
  • 1520-5207 (ISSN-L)
  • 1520-6106
OpenAlex
W2054059695
Cited by
302
References
0
FWCI
3.43
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Determination of Fracture Energy of High Strength Double Network Hydrogels. https://app.cochat.ai/papers/10.1021/jp0500790
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Tanaka, Y., Kuwabara, R., Na, Y.-H., Kurokawa, T., Gong, J. P., & Osada, Y. (2005). Determination of Fracture Energy of High Strength Double Network Hydrogels. The Journal of Physical Chemistry B. https://doi.org/10.1021/jp0500790

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