The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Characterization of Lithium Alkyl Carbonates by X-ray Photoelectron Spectroscopy: Experimental and Theoretical Study
Abstract
Lithium alkyl carbonates ROCO2Li result from the reductive decomposition of dialkyl carbonates, which are the organic solvents used in the electrolytes of common lithium-ion batteries. They play a crucial role in the formation of surface layers at the electrode/electrolyte interfaces. In this work, we report on the X-ray photoelectron spectroscopy (XPS) characterization of synthesized lithium methyl and ethyl carbonates. Using Hartree-Fock ab initio calculations, we interpret and simulate the valence spectra of both samples, as well as several other Li alkyl carbonates involved in Li-ion batteries. We show that Li alkyl carbonates can be identified at the electrode's surface by a combined analysis of XPS core peaks and valence spectra.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Advanced Model for Solid Electrolyte Interphase Electrodes in Liquid and Polymer Electrolytes
Peled, E., Golodnitsky, D., & Ardel, G. (1997) · Journal of The Electrochemical Society · doi:10.1149/1.1837858 · Cited by 1,205
Recent developments in lithium ion batteries
Wakihara, M. (2001) · Materials Science and Engineering R Reports · doi:10.1016/s0927-796x(01)00030-4 · Cited by 719
Cited by
Electrolytes and Interphases in Li-Ion Batteries and Beyond
Xu, K. (2014) · Chemical Reviews · doi:10.1021/cr500003w · Cited by 5,566
Cabana, J., Monconduit, L., Larcher, D., & Palacín, M. R. (2010) · Advanced Materials · doi:10.1002/adma.201000717 · Cited by 2,361
Wood, K. N., & Teeter, G. (2018) · ACS Applied Energy Materials · doi:10.1021/acsaem.8b00406 · Cited by 676
Michan, A. L., Parimalam, B. S., Leskes, M., Kerber, R. N., Yoon, T., Grey, C. P., & Lucht, B. L. (2016) · Chemistry of Materials · doi:10.1021/acs.chemmater.6b02282 · Cited by 541
Deciphering the multi-step degradation mechanisms of carbonate-based electrolyte in Li batteries
Gachot, G., Grugeon, S., Armand, M., Pilard, S., Guenot, P., Tarascon, J.-M., & Laruelle, S. (2008) · Journal of Power Sources · doi:10.1016/j.jpowsour.2007.11.110 · Cited by 425
Self-citation
Metadata
- Authors
- Dedryvère, R., Gireaud, L., Grugeon, S., Laruelle, S., Tarascon, J.-M., & Gonbeau, D.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-08-01
- Volume
- 109
- Issue
- 33
- Pages
- 15868-15875
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2061154638
- Cited by
- 355
- References
- 2
- FWCI
- 6.04
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Characterization of Lithium Alkyl Carbonates by X-ray Photoelectron Spectroscopy: Experimental and Theoretical Study. https://app.cochat.ai/papers/10.1021/jp051626k
- The paper
- Dedryvère, R., Gireaud, L., Grugeon, S., Laruelle, S., Tarascon, J.-M., & Gonbeau, D. (2005). Characterization of Lithium Alkyl Carbonates by X-ray Photoelectron Spectroscopy: Experimental and Theoretical Study. The Journal of Physical Chemistry B. https://doi.org/10.1021/jp051626k
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
