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Cited by 594

The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.

Oligothiophene-Containing Coumarin Dyes for Efficient Dye-Sensitized Solar Cells

Hara, Kohjiro, Wang, Zhong-Sheng, Sato, Tadatake, Furube, Akihiro, Katoh, Ryuzi, Sugihara, Hideki, Dan-oh, Yasufumi, Kasada, Chiaki, Shinpo, Akira, Suga, Sadaharu·2005·The Journal of Physical Chemistry B

Abstract

We have developed oligothiophene-containing coumarin dyes fully functionalized for dye-sensitized nanocrystalline TiO(2) solar cells (DSSCs). DSSCs based on the dyes gave good performance in terms of incident photon-to-current conversion efficiency (IPCE) in the range of 400-800 nm. A solar energy-to-electricity conversion efficiency (eta) of 7.4% was obtained with a DSSC based on 2-cyano-3-[5'-(1,1,6,6-tetramethyl-10-oxo-2,3,5,6-tetrahydro-1H,4H,10H-11-oxa-3a-aza-benzo[de]anthracen-9-yl)-[2,2']bithiophenyl-5-yl]acrylic acid (NKX-2677) under simulated AM 1.5G irradiation (100 mW cm(-2)) with a mask: short-circuit current density (J(sc)) = 13.5 mA cm(-2); open-circuit voltage (V(oc)) = 0.71 V; fill factor (FF) = 0.77. Transient absorption spectroscopy measurements indicated that electron injection from NKX-2677 to the conduction band of TiO(2) is very rapid (<100 fs), which is much faster than the emission lifetime of the dye (1.0 ns), giving a highly efficient electron injection yield of near unity.

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Crossref · 10.1021/jp0518557

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Metadata

Authors
Hara, K., Wang, Z.-S., Sato, T., Furube, A., Katoh, R., Sugihara, H., Dan-oh, Y., Kasada, C., Shinpo, A., & Suga, S.
Venue
The Journal of Physical Chemistry B
Published
2005-07-27
Volume
109
Issue
32
Pages
15476-15482
ISSN
  • 1520-5207 (ISSN-L)
  • 1520-6106
OpenAlex
W2013687287
Cited by
594
References
1
FWCI
15.90
Type
journal article
Language
en
Open access
closed

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