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Cited by 350

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Quasicubic α-Fe2O3 Nanoparticles with Excellent Catalytic Performance

Zheng, Yuanhui, Cheng, Yao, Wang, Yuansheng, Bao, Feng, Zhou, Lihua, Wei, Xiaofeng, Zhang, Yingying, Zheng, Qi·2006·The Journal of Physical Chemistry B

Abstract

Uniform quasicubic alpha-Fe(2)O(3) nanoparticles enclosed by six identical {110} planes were synthesized by a simple solvothermal method. TEM investigations revealed that they were formed through oriented attachment of primary nanocrystals assisted by Ostwald ripening, and PVP surfactant played an important role in control over the final morphology of the products. These quasicubic nanoparticles could catalyze oxidation of almost 100% CO at a temperature of 230 degrees C, much lower than those of nanophases with flowerlike, hollow, or other forms of irregular external morphologies having various crystal planes exposed to the gas, indicating that the external morphology and especially the exposure crystal planes of alpha-Fe(2)O(3) nanocatalyst affect the catalytic activity more significantly than the traditionally accepted factors (such as high BET surface area, hollow structure, etc.) do for CO catalytic oxidation.

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Metadata

Authors
Zheng, Y., Cheng, Y., Wang, Y., Bao, F., Zhou, L., Wei, X., Zhang, Y., & Zheng, Q.
Venue
The Journal of Physical Chemistry B
Published
2006-01-31
Volume
110
Issue
7
Pages
3093-3097
ISSN
  • 1520-5207 (ISSN-L)
  • 1520-6106
OpenAlex
W2329078179
Cited by
350
References
1
FWCI
13.02
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Quasicubic α-Fe2O3 Nanoparticles with Excellent Catalytic Performance. https://app.cochat.ai/papers/10.1021/jp056617q
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Zheng, Y., Cheng, Y., Wang, Y., Bao, F., Zhou, L., Wei, X., Zhang, Y., & Zheng, Q. (2006). Quasicubic α-Fe2O3 Nanoparticles with Excellent Catalytic Performance. The Journal of Physical Chemistry B. https://doi.org/10.1021/jp056617q

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